Application of Hydrocarbons as Markers for Detecting Post-irradiation of Imported Meats and Fish

수입육류 및 어류의 방사선조사 여부 판별을 위한 Marker로 검출되는 Hydrocarbons의 활용

  • 황금택 (전북대학교 식품영양학과 및 유전공학연구소) ;
  • 박준영 (전북대학교 식품공학과) ;
  • 김충기 (전북대학교 식품공학과)
  • Published : 1997.12.01

Abstract

Hydrocarbons were analyzed in irradiated beef, pork, dried and seasoned beef, dried anchovy, dried squid, dried shrimp, and fish paste to determine whether the hydrocarbons can be used as markers for detecting post-irradiation of the imported meat and fish products. The samples were irradiated at 0.5, 1, 3, and 6 kGy. Fat was extracted with hexane, and hydrocarbons were separated from the fat through Florisil column. The hydrocarbons were analyzed with GC. Hydrocarbons 15:0, 16:1, 17:1, 16:2, 17:2, and 16:3 in beef and pork, 17:1, 16:2, and 17:2 in dried and seasoned beef, 16:2 in dried anchovy, 16:1 and 17:1 in dried squid, 16:1, 17:1, and 16:2 in dried shrimp, and 16:1, 16:2, and 16:3 in fish paste were detected in the irradiated samples, but not in the unirradiated, so that the hydrocarbons may be used as makers for detecting post-irradiation of each item.

Keywords

References

  1. Facts about food irradiation ICGFI
  2. Wholesomeness of Irradiated Food WHO Technical Report Series WHO
  3. Federal Register v.51 irradiation in the production, processing, and handing of food FDA
  4. 식품위생정보 52호 식품의 기준 및 규격 중 개정 고시(보건복지부 고시 제1995-34호) FSN
  5. Int. J. Food Sci. Technol. v.22 The identificationof irra-diated spices with thermo- and chemiluminescence measurements Heide, L.;Bogl, K W.
  6. Food Structure v.12 Luminescence techniques to idenitify the treatment of foods by ionizing irradiation Schreiber, G. A.;Ziegelmann, B.;Quitzsch, G,lHelle, N.;Bogl, K. W.
  7. JAOAC International v.78 An inter-laboratory trial on the identification of irradiated spi-ces, herbs.and spice-herb mixtures by thermolumine-scence analysis Schreiber, G. A.;Helle, N.;Bogl, K W.
  8. Radiat Phys Chem. v.43 Methods for routine control of irradiated food:determination of the irradiation status of shellfish by thermoluminescence analysis Schreiber, G. A.;Hoffmann, A.;Helle, N.;Bogl, K. W.
  9. Int. J. Food Sci. Technol v.23 A method of testing for irradiation of poultry Lea, L. S.;Dodd, N. J. F.;Swallow, A J.
  10. J Agric. Food Chem. v.36 Postirradiation dosimetry of meat by electron spin resonance spec-troscpy of bones Desrosiers, M. F.;Simic, M. G.
  11. Food Science v.34 The volatille components of irradiated beef and pork fats Champagne, J. R.;Nawar, W W.
  12. Recent advances on the detection of irradiated food, BcR Informantion, EUR/14315/EN identification of radiation-induced volatiles in meat. Comparison of two isolation methods:high vacuum 'cold finger' distillation and florsil ch-romatography Schulzki, G.;Spiegelberg, A.;Helle, N.;Bogl, K. W.;Schreiber, G. A.;lenardi, M.(ed.);Raffi, J. J.(ed.);Belliardo, J. J.(ed.)
  13. Radiat. Phys. Chem. v.31 Chromatographic and electron spin resonance investigations of gamma-irradiated frog legs Morehouse, K M.;KU, Y;Albrecht, H. L.;Yang, G. C.
  14. JAOCS v.70 use of radiation-induced alkanes and alkenes to detect irradiated food con-taining lipids Lesgards, G.;Raffi, J.;Pouliquen, I.;Chaouch, A A.;Giamarchi, P;Prost, M.
  15. Radial. Phys. Chem. v.43 Methods for routine control of ir-radiated food:optimization of a method for detection or radiation-induced hydrocarbons and its application to various foods Spiegelberg, A.;Schulzki, G.;Helle, N.;Bogl, K. W.;Schreiber, G. A.
  16. JAOAC International v.77 Evaluation of a gas chroma-tographic method to identify irradiated chicken, pork, and beef by detection of volatile hydrocarbons Schreiber, G. A,lSchulzki, G;Spiegelberg, A;Helle, N;Bogl, K. W.
  17. J. Agric Food Chem. v.43 Detection of radiation-induced hydro-carbons in camembert irradiated before and after the maturing process-comparison of Florisil column ch-romatography and on-line coupled liquid chromato-graphy-gas chromatography Schulzki, G;Spiegelberg, A.;Bogl, K. W.;Schreiber, G. A.
  18. JAOCS v.74 Detection of hydro-carbons in irradiated and roasted sesame seeds Choi, C. R.;Hwang, K. T.
  19. J. Agric Food Chem. v.39 Synthe-sis, characterization, and potential use of 2-dodecyl-cyclobutanone as a marker for irradiated chicken Boyd, D. R.;Crone, A. V J;hamilton, J T. G;Hand, M. V;Stevenson, M. H.;Stevenson, P. J.
  20. J Sci. Food Agric v.58 Effect of storage and cooking on the dose res-ponse of 2-dodecylcyclobutanone, a potential marker for irradiated chicken Crone, A. V. J.;Hamlton, J T G;Stevenson, M. H.
  21. JAOCS v.54 Effects of tonizing radiation on some vegetable fats Kavalam, J R.;Nawar, W. W
  22. J. Agric Food Chen. v.17 Effects of high-energy radiation on the lipids of fish Dubravcic, M. F.;nawar, W. W>
  23. Food irradiation and the chemist Radiolytic products of lipids as marker for the detection of irr-adiated mear Nawar, W. W.;Zhu, Z. R.;Yoo, Y. J.;johnston, D. E.(ed.);Stevenson, M. H.(ed.)
  24. Bailey's industrial oil and fat products. Edible oil and fat procucts, General applications(5th ed.) v.1 Lipid composition of selected foods Hands, E S;Hui, Y H.(ed.)
  25. Supplement to Food Irradiation Newsletter v.19 no.2 IAEA