Effect of Addition of Boron Carbide on the Graphitization and Oxidation Resistance of Raw Cokes

Raw Cokes의 흑연화 및 내산화성에 미치는 $B_4C$첨가 효과

  • Published : 1997.04.01

Abstract

The specimens which were prepared from cokes with additions of 0~25 wt% B4C were sintered in Ar atmosphere at 220$0^{\circ}C$. The effects of B4C content on graphitization and oxidation resistance of cokes were investigated. B4C accelerates the graphitization of cokes and at 220$0^{\circ}C$ the degree of graphitization increased from 0.33 which is the value of pure carbon to 0.56, which increased bluk density and porosity. Especially bending strength increased as th graphitization temperature increased. Oxidation resistance property was greatly improved when B4C was added more than 10wt% at 80$0^{\circ}C$ and when B4C was added more than 20wt% at 100$0^{\circ}C$. This was because that the thin layer of B2O3 glass phase on the surface of the composite could be identified to increase the oxidation resistance.

Keywords

References

  1. 요업학회지 v.31 no.1 탄소재 제조에 있어서 Raw cokes의 전처리 영향 염희남;황인수;김경자;정윤중
  2. J. Mater. Sci. v.16 Graphite and boron composites made by hot-pressing Kenji Miyazaki;Tsuyoshi Hagio;Kazuo Kobayashi
  3. 炭素 no.111 Effect of Hot-pressing Pressure on Some Properties of Polysrystalline Graphite Kenji Miyazaki;Tsuyoshi Hagio;Kazuo Kobayashi
  4. 炭素 no.124 High Temperature Electrical Resistritity and Thermal Expansion Coefficient of High Dense Carbons and Carbon-Ceramic Composites Kenji Miyazaki;Tsuyoshi Hagio;Kazuo Kobayashi
  5. Yogyo-Kyokai-Shi v.84 no.11 Isotropic, High-Dense Carbon Blocks Prerared from Low Distillated Pitch-cokes Susumu Mukohara;Hiroshige Suzuki
  6. J. Mater. Sci. v.23 Oxidation Resistance of C-SiC-B₄C Composite in Air Ichitaro Ogawa;Kazuo Kobayashi
  7. J. Am. Ceram. Soc. v.50 no.3 Solid Solution of Boron in Graphite C.E. Lowell
  8. carbon Kim Kinoshita
  9. Chemistry and Physics of Carbon v.19 Substitutional Solid Solubility in Carbon and Graphite S. Marinlovic;Pillip L. Walker,JR.(ed.);peter A. Thrower(ed.)
  10. Chemistry and Physics of Carbon v.7 The kinetics of graphitization A. Pacault;Pillip L. Walker,JR.(ed.);peter A. Thrower(ed.)
  11. 化學大辭典 v.3