Microstructures and Electrical Properties of $RuO_2$Bottom Electrode for Ferroelectric Thin Films

  • Published : 1997.12.01

Abstract

RuO$_3$ thin films were deposited on Si(100) substrate at low temperatures by hot-wall metalorganic chemical vapor deposition. Bis(cyclopentadienyl) ruthenium, Ru$(C_5H_5)_2$, was used as the precursor RuO$_2$single phase was obtained at a low deposition temperature of 25$0^{\circ}C$ and the crystallinity of RuO$_2$thin films improved with increasing deposition temperature. RuO$_2$thin films grow perpendicularly to the substrate and show the columnar structure. The grain size of RuO$_2$films drastically increases with increasing the deposition temperature. The resistivity of the 180 nm-thick RuO$_2$thin films deposited at 27$0^{\circ}C$ was 136 $\mu$$\Omega$-cm and increased with decreasing film thickness. SrBi$_2Ta_2O_4$ thin films deposited by rf magnetron sputtering on the RuO$_2$bottom electrodes showed a fatigue-free characteristics up to ~10$^10$ cycles under 5 V bipolar square pulses and the remanent polarization, 2 P$_r$ and the coercive field, 2 E, were 5.2$\mu$C/$\textrm{cm}^2$ and 76.0 kV/cm, respectively, for an applied voltage of 5 V The leakage current density was about 7.0$\times$10$^{-6}$ A/$\textrm{cm}^2$ at 150 kV/cm.

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References

  1. Science v.246 J.F. Scott;C.A. Paz de Araujo
  2. Ferroelectrics v.108 S.K. Dey;Zuleeg
  3. J. Appl. Phys. v.79 H.N. Al-shareef;B.A. Tuttle;W.L. Warren;T.J. Headley;D.Dimos;J.A. Voigt;R.D. Nasby
  4. J. Electrochem. Soc. v.132 M.L. Green;M.E. Gross;L.E. Papa;K.J. Schnoes;D. Brasen
  5. Appl. Phys. Lett, v.50 L. Krusin-Elbaum;M. Wittmer;D.S. Yee
  6. J. Mater. Res. v.9 Q.X. Jia;L.H. Chang;W.A. Anderson
  7. Appl. Phys. Lett. v.66 H.N, Al-Shareef;K.R. Bellur;A.I. Kingon;O. Auciello
  8. Thin Solid Films v.238 S.Y. Mar;J.S. Liang;C.Y. Sun;Y.S. Huang
  9. J. Mater. Res. v.8 J. Si;S.B. Desu
  10. Thin Solid Films v.173 E. Kolawa;F.C.T. So;W. Flick;X.A. Shao;E.T.S. Pan;M.A. Nicolet
  11. Thin Solid Films. v.205 T.S. Kalkur;Y.C. Lu
  12. Phys. Rev. B. v.1 A.F. Mayadas;M. Shatzkes
  13. Acta Cryst. B. v.48 A.D. Rae;J.G. Thompson;R.L. Withers
  14. Mater. Sci. Eng. B. v.32 S.B. Desu;d.P. Vijay