Properties of Silicon Carbide-Carbon Fiber Composites Prepared by Infiltrating Porous Carbon Fiber Composites with Liquid Silicon

  • Lee, Jae-Chun (Department of Inorganic Materials Engineering, Myong Ji University) ;
  • Park, Min-Jin (Department of Inorganic Materials Engineering, Myong Ji University) ;
  • Shin, Kyung-Sook (Department of Inorganic Materials Engineering, Myong Ji University) ;
  • Lee, Jun-Seok (Department of Inorganic Materials Engineering, Myong Ji University) ;
  • Kim, Byung-Gyun (Department of Inorganic Materials Engineering, Myong Ji University)
  • 발행 : 1997.12.01

초록

Silicon carbide-carbon fiber composites have been prepared by partially Infiltrating porous carbon fiber composites with liquid silicon at a reaction temperature of $1670^{\circ}C$. Reaction between molten silicon and the fiber preform yielded silicon carbide-carbon fiber composites composed of aggregates of loosely bonded SiC crystallites of about 10$\mu\textrm{m}$ in size and preserved the appearance of a fiber. In addition, the SiC/C fiber composites had carbon fibers coated with a dense layer consisted of SiC particles of sizes smaller than 1$\mu\textrm{m}$. The physical and mechanical properties of SiC/C fiber composites were discussed in terms of infiltrated pore volume fraction of carbon preform occupied by liquid silicon at the beginning of reaction. Lower bending strength of the SiC/C fiber composites which had a heterogeneous structure in nature, was attributed to the disruption of geometric configuration of the original carbon fiber preform and the formation of the fibrous aggregates of the loosely bonded coarse SiC particles produced by solution-precipitation mechanism.

키워드

참고문헌

  1. The Preparation of Dense Self-Bonded Silicon Carbide P. Popper
  2. Brit. Ceram. Res. Ass. Stoke-on-Trent The Fabrication and Properties of Self-Bonded Silicon Carbide Bodies(Vol. 5) C.W. Forrest;P. Kennedy;J.V. Shennan
  3. J. Mat. Sci. v.23 Strength Variation of Reaction-Sintered SiC Heterogeneously Containing Fine-GRained β-SiC C.B. Lim;T. Iseki
  4. Ceram. Inter. v.20 Influence of Grain Size, Free Silicon Content and Temperature on the Strength and Toughness of Reaction-Bonded Silicon Carbide O.P. Chalkrabarti;S. Ghosh, J. Mukerji
  5. Mat. Sci. Eng. v.A144 Reaction-formed Silicon Carbide Y.M. Chiang;R.P. Messner;C.D. Terwilliger;D.R. Behrendt
  6. J. Korean. Ceram. Soc. v.30 no.1 Properties of Reaction-Bonded Silicon Carbide Depending on Graphite Aditions I.S. Han;J.H. Yang;D.S. Suh
  7. J. Korean Ceram. Soc. v.20 no.2 Reactive Sintering of SiC Y.W. Kim;J.G. Lee
  8. J. Korean. Asso. Cryst. Growth. v.4 no.4 A Study on the REaction Between Silicon in Melt and Carbon M.J. Lee;B.J. Kim;S.M. Kang;J.K. Choi;B.S. Jeon;K.H. Orr
  9. Am. Ceram. Soc. Bull. v.73 no.4 Making Ceramic Composites by Melt Infiltration W.B. Hilig
  10. Am. Ceram. Soc. Bull. v.72 no.7 Toughened Silicomp Composites-Process and Preliminary Properties K.L. Luthra;R.N. Singh;M.K. Brun
  11. Am. Ceram. Bull. v.54 no.12 Silicon/Silicon Carbide Composities W.B. Hillig;R.L. Mehan;C.r. Morelock, V.J. Decarlo;W. Laskow
  12. Am. Ceram. Bull. v.64 no.5 Caron-Bonded Carbon Fiber Insulation for Radiosotope Space Power Systems G.C. Wei;N. Robbion
  13. J. Am. Ceram. Soc. v.80 no.1 Preparation and Compressive Strength Behavior of Porous Ceramics with $β-Ca(PO_3)_2$ Fiber Skelectons Y. Ota;T. Kasuga;Y. Abe
  14. Ceram. Int. v.12 Reaction Mechanism in Carbon-Liquid Silicon Systems at Elevatied Temperature R. Pampuch;E.Walasek;J. Bialoskorski