Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Melting and Non-isothermal Crystallization Behaviors of Poly (trimethylene Terephthalate)

폴리(트리메틸렌 테레프탈레이트)의 용융 및 비등온 결정화 거동

  • Kim, Yeong-Ho (Dept. of Textile Eng., College of Eng., Soong-Sil Univ.) ;
  • Kim, Gap-Jin (Dept. of Textile Eng., College of Eng., Soong-Sil Univ.)
  • Published : 1997.12.01

⟨ Previous Next ⟩

Abstract

Poly(trimethylene terephthalate)(PTMT), which is expected to be used as a new polyester fiber, was polymerized from terephthalic acid and 1,3-propanediol and its basic thermal roperties such as glass transition temperature(Tg), melting temperature(Tm) and non-isothermal crystallization behaviors were investigated by differential scanning calorimetry(DSC). Tg of PTMT was 39.5 ℃, which is much lower than that of PET. The equilibrium melting temperature of 244.1 ℃ was obtained from Hoffman-Weeks plots. Multiple melting curves were observed both in isothermally and non-isothermally crystallized samples. In non-isothermal crystallization, the Aramid exponent of about 2.7 and the activation energy of 165 kl/mol were obtained by using 03awa's modified Aramid equation.

Keywords

References

  1. Encyclopedia of Polymer Science and Engineering v.10 H. F. Mark(et al.)
  2. Polymer v.7 S. Arnott;A. J. Wonacott
  3. Polymer v.20 I. J. Desborough;I. H. Hall;J. Z. Neisseer
  4. Macromolecules v.20 B. J. Bulkin;M. Lewin;J. Kim
  5. Polymer v.17 I. H. Hall;M. G. Pass
  6. J. Polym. Sci.: Polym. Phys. Ed. v.24 J. S. Kim;M. Lewin;B. J. Bulkin
  7. J. Appl. Polym. Sci. v.32 T. Hwee Ng;H. L. Williams
  8. J. Polym. Sci.: Polym. Phys. Ed. v.26 C. C. Gonzalez;J. M. Perena;A Bello
  9. Makromol. Chem. v.184 E. Ponnusamy;T. Barakrishnan;H. Kothandaraman
  10. EP., 385,428 Du Pont
  11. J. Polym. Sci.: A-1 v.4 J. G. Smith;C. G. Kibler;B. J. Sublett
  12. J. Res. Natl. Bur. Stand. v.66A J. D. Hoffman;J. J. Weeks
  13. J. Appl. Polym. Sci. v.23 W. Marrs;R. H. Peters;R. H. Still
  14. J. Polym. Sci. : Polym. Phys. v.32 R. L. Scherrenberg;H. Reynaers;C. Gondard;P. A. M. Steeman
  15. Polymer Handbook(3rd Ed.) J. Brandrup;E. H. Immergut
  16. Kobunshi Ronbunshu v.32 K. Kamide;A. Imanaka
  17. J. Polym. Sci.: Symp. v.71 S. B. Lin;J. L. Koenig
  18. J. Polym. Sci.: Polym. Phys. Ed. v.30 M. E. Nichols;R. E. Robertson
  19. Polym. Eng. Sci. v.28 Y. P. Khanna;T. J. Taylor
  20. Polymer v.12 T. Ozawa
  21. J. Appl. Polym. Sci. v.47 M. Patkar;S. A. Jabarin
  22. J. Appl. Polym. Sci. v.34 S. A. Jabarin