Preparation of Uranium and Heavy Metal ion Adsorbents from Cotton-Knit-Waste(I) - Preparation of a Highly Cyanoethylated Cotton Waste and Its Amidoximation for Uranium and Heavy Metal ion Adsorption

폐면으로부터 우라늄 및 중금속 이온 흡착제의 제조(I) -고치환 시아노에틸화 폐면의 제조와 우라늄 및 중금속 이온흡착을 위한 아미드옥심화-

  • Mun, Seong-Pil (Dept. of Forest ProductsChonbuk National University) ;
  • Han, Yong-Bong (Dept. of Textile Eng. College of Eng., Chonbug Nayional Univ, Chonju Korea)
  • 문성필 (전북대학교 농과대학 임산공학과) ;
  • 한용봉 (전북대학교 공과대학 섬유공학과)
  • Published : 1997.06.01

Abstract

The cotton-knit-waste which was composed of 95% of $\alpha$-cellulose was chemically modified to make it bind uranium and heavy metal ions. The highly cyanoethylated cotton waste (CE cotton waste, over D.S. 2.5) was prepared when cotton-knit-waste was pretreated with 30% NaOH solution at room temperature for 30 minute and then diluted to 10% NaOH solution without using the swelling agent such as NaSCN. The amidoximated cotton waste (AO cotton waste) was prepared by the reaction of CE cotton waste with hydroxylamlne in methanol for 4 hr at 67$^{\circ}C$. CE cotton waste was converted to the AO cotton waste with a conversion of 84%. The structure of CE and AO cotton waste was identified by IR spectroscopy.

Keywords

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