Interfacial Adhesion Improvement of Liquid Crystalline Copolyester and Polyimide by Plasma Surface Treatment

플라즈마 표면처리에 의한 폴리에스테르계 액정고분자와 폴리이미드의 계면 접착성 향상

  • 김성훈 (한양대학교 섬유공학과) ;
  • 박정희 (서울대학교 의류학과, 경기대학교 재료공학과)
  • Published : 1997.04.01

Abstract

Plasma surface modifications were performed on the aromatic copolyester liquid crystalline polymer surface to improve adhesivity to the polyimide matrix. Oxygen or ammonia plasma treatment on the liquid crystal polymer was fairly stable for one month, which was continuously confirmed by variation of contact angle. Peel strength test was employed to determine adhesivity between LCP and polyimide, and sessile drop contact angle was measured to study the surface properties of the plasma treated liquid crystal polymers. The surface morphologies of the plasma treated liquid crystal polymers were investigated as well. A mixture of 95% ammonia and 5% hydrogen plasma treatment on the liquid crystal polymer provided greatly improved adhesivity to polyimide.

Keywords

References

  1. ACS Polym. Prepr. v.33 S. H. Kim;S. P. Sawan
  2. Korea Polym. J. v.2 S. H. Kim;S. P. Sawan
  3. Plastics Eng. v.44 S. L. Kaplan
  4. Polym. Mat. Sci. Eng. v.62 R. A. Engelman;H. K. Tasuda
  5. J. Poly. Sci. Part A v.3 R. H. Hansen;J. V. Pascale;T. De Benedictis;P. M. Rentzepis
  6. The First Annual Int. Conf. Plasma Chem. Tech. H. V. Boenig
  7. Polym. Mat. Sci. Eng. v.64 S. R. Gaboury;M. W. Urban
  8. Mol. Cryst. Liq. Cryst. v.169 M. C. Muir;R. S. Porter
  9. Poly. Eng. Sci. v.29 F. P. La Mantia;A. Valenza
  10. High Performance Polymers: Their Origin and Development G. W. Calundann;R. B. Seymour;G. S. Kirshenbaum(ed.)
  11. Poly. Eng. Sci. v.27 G. Kiss
  12. Poly. Eng. Sci. v.27 G. Kiss
  13. ACS, Adv. Chem. Ser. no.43 Contact Angle, Wettability and Adhesion W. A. Zisman;F. M. Fowkes(ed.)
  14. Adv. Chem. Ser. no.43 Contact Angle, Wettability, and Adhesion W. A. Zisman;F. M. Fowkes(Ed.)
  15. ACS Polym. Prepr. v.31 no.1 E. Occhiello;M. Morra;P. Cinquina;F. Garbassi
  16. J. Polym. Sci. v.19 K. Rossmann
  17. Tech. Appl. Plasma Chem. H. Suhr;J. R. Hollahan;A. T. Bell(ed.)
  18. ACS v.D.C. Metallization of Polymers K. W. Lee;S. P. Kowalczyk
  19. Polym. Sci. Tech. v.28 E. G. Joseph;G. L. Wilkes;D. G. Baird
  20. Polym. Sci. Tech. v.28 E. G. Joseph;G. L. Wilkes;D. G. Baird