SOLVATOCHROMIC BEHAVIOUR OF DONOR-ACCEPTOR SUBSTITUTED 1,2-DIPHENYLETHENES IN ORGANIC SOLVENTS, REVERSE MICELLES AND POLYMER MATRIX

  • Singh, A.K. (Department of Chemistry, Indian Institute of Technology Powai) ;
  • Mahalaxmi, G.R. (Department of Chemistry, Indian Institute of Technology Powai) ;
  • Malimath, G.H. (Department of Chemistry, Indian Institute of Technology Powai)
  • Published : 1997.06.01

Abstract

Absorption and fluorescence studies of E-1-(p-methoxyphenyl)-2-(p-nitrophenyl) ethene in homogeneous solvents, polymer matrix and normal and reverse micelles showing strong solvatochromic fluorescent emission properties with quasi-planar intramolecular charge transfer characteristics in the electronically excited singlet state are discussed.

Keywords

References

  1. Excited States v.6 Hudson, B. S.;B. E. Kohler;K. Schulten;E. C. Lim(ed.)
  2. Chem. Rev. v.91 The photophysics and photochemistry of α, ω-diphenylpolyene singlet states Allen, M. T.;D. G. Whitten
  3. Photochromism : Molecules and systems Saltiel, J.;Y. P. Sun;H. Durr(ed.);Bouas - Laurent(ed.)
  4. Chem. Rev. v.91 Photoisomeriszation dynamics of stilbenes Waldek, D. H.
  5. Acc. Chem. Res. v.26 Photochemistry and photophysics of trans-stilbene and related alkenes in surfactant assemblies Whitten, D. G.
  6. Adv. Photochem. v.12 The photophysics of rhodopsin Ottolenghi, M.
  7. Photochem. Photobiol. v.48 The visual process : photophysics and photoisomerization of model visual pigments and the primary reaction Becker, R. S.
  8. Biochim. Biophys. Acta v.293 Nature of the primary photochemical events in rhodopsin and bacteriorhodopsin Birge, R. R.
  9. J. Am. Chem. Soc. v.107 Micelle and vesicle solubilization sites. Determination of micropolarity and microviscosity using photophysics of a dipolar olefin Schanze, K. S.;D. M. Shin;D. G. Whitten
  10. J. Phys. Chem. v.92 Solvatochromic behavior of intramolecular charge transfer diphenylpolyenes in homogeneous and microheterogeneous media Shin, D. M.;D. G. Whitten
  11. Rearrangements in Ground and Excited States Saltiel, J.;J. L. Charleton;P. de Mayo(ed.)
  12. J. Am. Chem. Soc. v.90 Temperature dependence of photoisomerization. Ⅴ. The effect of substituents on the photoisomerization of stilbenes and azobenzenes Gegiou, D.;K. A. Muszkat;E. Fisher
  13. J. Phys. Chem. v.92 Fluorescence properties of 2,3-diarylindenes Anstead, G. M.;J. A. Katzenellenbogen
  14. J. Phys. Chem. v.93 Trans-cis photoisomerization, fluorescence and relaxation phenomena of trans-4 -nitro-4 -(dialkylamino)stilbene and analogues with a non-rotatable amino group Gruen, H.;H. Gorrer
  15. J. Chem. Phys. v.80 Picosecond study of an intermediate in the trans to cis isomerisation pathway of stiff stilbene Doany, F. E.;E. J. Heilweil;R. Moore;R. M. Hochstrasser
  16. Chem. Phys. Lett. v.30 Model for the direct photoisomerization of stilbenes Orlandi, G.;W. Siebrand
  17. J. Org. Chem. v.30 The stereochemistry of the phosphonate modification of the Wittig reaction Wadsworth, D. H.;O. E. Schupp, Ⅲ;E. J. Seus;J. A. Ford, Jr.
  18. J. Phys. Chem. v.94 Solvent-Tuned intramolecular charge-recombination rates in a conjugated donor-acceptor molecule Khundkar, L. R.;A. E. Stiegman;J. W. Petry
  19. J. Chem. Phys. v.37 Relationship between absorption intensity and fluorescence lifetime of molecules Strickler, S. J.;R. A. Berg