Gamma-Irradiated Ultra-high Molecular Weight Polyethylene : Anisotropic Changes in Crystallinity and Crosslinking

  • Lee, Kwon-Yong (University of Kentucky, Division of Orthopaedic Surgery)
  • Published : 1997.06.01

Abstract

The effect of gamma-irradiation sterilization on molecular structural changes in orthopaedic surgical-grade polyethylene was studied. The relative crystallinity ud. percent crosslinking of the substance increased as a result of the gamma irradiation and varied anisotropically as a function of depth. Samples from the articulating surfaces showed 5% Venter relative crystallinity than those from the mid-sections, whereas samples from the mid-sections exhibited 15% greater crosslinking than those from the surfaces. These anisotropic variations are discussed in assDciation with oxidation.

Keywords

References

  1. Clin. Crthop. v.311 The problem is osteolysis W. H. Harris
  2. J. Bone Joint Surg. v.75-A The problem in total joint arthroplasty: Aseptic loosening (Editorial) S.R. Goldring;C.R.Clark;T.M. Wright
  3. Clin Orthop. v.276 Mechanism and clinical significance of wear debris-induced osteolysis H.C. Amstutz;P.Campbell;N.Kossovsky;I.C.Clasrke
  4. J. Biomed. Mater. Res. v.13 The efects of radiation sterilization on the properties of ultrahigh molecular weight polythylne H.J. Nusbaum;R.M. Rose
  5. J. Biomed. Mater. Res. v.15 Effect of radiation sterilization and aging on ultrahihg molecular weight polythylene R. J. Roe;E.S. Grood;R. Shastri;C.A. Gosselin;F.R. Noyes
  6. Radiat. Phys. Chem. v.26 no.6 Effect of radiation on the structure of ultrahigh molecular weight polyethylene I. Kamel;L. Finegold
  7. Mater. Chem. Phys. v.14 The effect of sterilising radiation on the properties of ultra-high molecular weight polyetylene C. Birkinshaw;M. Buggy;J. J. White
  8. ANTEC'87, Conf. Proc. Soc. Plast. Eng. 45th Effects of radiation sterilization on UHMW-polyethylene M. Kurth;P.Eyerer;D. Cui
  9. Plastics ad Rubber Processing and Applications v.10 Ionizing irradiation for sterilization and modification of high molecular weight polyethylenes R.M. Streicher
  10. Radiat. Phys. Chem. v.31 no.4;5;6 Influence of ionizing irradiation in air and nitrogen for sterilization of surgical grade polyethylene for implants R.M. Streicher
  11. J. Appl. Polym. Sci. v.38 The effect of gradiation on the physical structure and mechanical properties of ultrahigh molecular weight polyethylene C. Birkinshaw;M. Buggy;S. Daly
  12. Wear v.10 Teh wear properties of high-density polyethylene irradiated by gamma rays K. Matsubara;M. Watanabe
  13. Wear v.30 The friction and wear behavior of irradiated very high molecular weight polyethylene C. Shen;J.H. Dumbleton
  14. J. Orthop. Res. v.2 Radiation sterilization and the wear rate of polyethylene R. M. Rose;E. V. Goldfarb;E. Ellis;A.N. Crugnola
  15. J. Bone Joint Surg v.60-B The radiation improvement of polyethylene prostheses, a preliminary study C.J. Grobbelaar;T.A. Du Plessis;F. Marais
  16. Wear v.77 Exploratory investigations on the structure dependence of the wear resistance of polyethylene R.M. Rose;W.R. Cimino;E. Ellis;A.N. Crugnola
  17. Radit. Phys. Chem. v.39 no.6 improvement of polythylene by irradiation in artificial joints H. Oonishi;Y. Takayama;E. Tsuji
  18. J. Biomed. Mater. Res. Compressive creep characteristics of extruded ultrahigh molecular weight polythylene K.-Y. Lee;D. Pienkowski
  19. Biomaterials v.17 Morphology of rodstock and compression-moulded sheets of ultra-high-molecular-weight-polyethylene used in orthopaedic implants A. Bellare;R.E. Cohen
  20. J. Biomed. Mater. Res. v.18 Property changes of UHMW polyethylene hip cup endoprostheses during implantation P. Eytrt;Y.C. Ke
  21. Biomaterials v.14 Challenge to the concept that UHMWPE acetabular components oxidize in vivo S.P. James;S. Blazka;E.W. Merrill;M. Jasty;K. R. Lee;C.R. Bragdon;W.H. Harris
  22. J. Bone Joing Surg. v.76-A Post-irradiation aging of ultra-high molecular weight polyethylene C.M. Rimnac;R.W. Klein;F.Betts;T.M. Wright
  23. Clin. Orthop. v.319 The Otto Aufranc Award. Impact of gamma sterilization on clinical performance of polyethylene in the hip L.C. Sutula;J.P. Collier;K.A. Saum;B.H. Currier;J.H. Currier;W. M. Sanford;M.B. Mayor;R.E. Wooding;D.K. Sperling;I.R. Williams;D.J. Kasprzak;V.A. Surprenant
  24. J. Polymenr Sci. v.A-25 Heat of fusion of polyethylene B. Wunderlich;C.M. Cormier
  25. D 2765-90 Standard test methods for determination of gel content and swell ratio of crosslinked etylene plastics ASTM
  26. GUR TADS/Method 18 Determinationof percent crosslinking in polyethylene Hoechst Celanese
  27. Radit. Phys. Chem. v.29 no.1 Crystallinity dependent free radical formation and decay i irradiated polyethylene i the presence of oxygen R. Hikmet;A. Keller
  28. Radit. Phys. Chem. v.22 no.1;2 Radiation effects and crystallinity in polythylene A. Keller;G. Ungar
  29. J Polym. Sci.: Polym. Phys. Ed. v.23 Irradiation of ultrahigh-molecular-weight polyethylene A. Shinde;R. Salovery
  30. J Polym. Sci.:Polym. Phys. Ed. v.21 Radiation-induced rystallinity changes in linear polyethylene S.K. Bhateja;E.HJ. Andrews;R.J. Young
  31. J. Appl. Phys. v.35 Irradiation of annealed polyethylene crystals R. Salovey;D.C. Bassett
  32. Trans. of the 43rd Ann. Meet. Orthop. Res. Soc. Shelf-life effects of crosslinking of UHMWPE A. Patel;K.-Y.Lee;D.Hamilton;J. Higgins;D. Schroeder;D. Pienkowski
  33. 5th World Biomat. Cong. Oxidative degradation and embrittlement of ultrahigh molecular wieght polyethylene, analysis of 107 COMPONENTS O. Muratoglu;A. Liu;M. Jasty;C.R. Bragdon;J. R. Elder;W.H. Harris
  34. J. of Arthroplasty v.10 Preliminary study of the effect of aging following irradiation in the wear of ultrahigh-molecular-weight polyethylene J. Fisher;K.L. Chan;J.L. Hailey;D. Shaw;M. Stone
  35. 5th World Biomat. Cong. Effects of sterilizatio methods on the wear of ultra-high molecular weight polyethylene acetabular cups A. Wang;D.C. sUN;C. Stark;J.H. Dumbleton