Nucleation and Growth of b-Axis Oriented $PrBa_2Cu_3O_{7-x}$ Thin Films on $LaSrGaO_4$ (100) Substrates

  • Published : 1997.01.31

Abstract

Good quality a-axis oriented thin films of $YBa_2Cu_3O_{7-x}$ may be grown by the use of a $PrBa_2Cu_3O_{7-x}$ (PBCO) layer as a template. Here we present a detailed study of the nucleation of the PBCO layer, explaining the orientations observed. It is determined that the wavy surface of a $LaSrGaO_4$ (LSGO) (100) substrate consists of the {101} planes by observing cross-sectional transmission electron microscopy images of the interface between the PBCO film and the substrate. The images and selected area diffraction patterns show that a mixed c-and b-axis oriented PBCO layer was initially grown on the substrate, followed by pure b-axis oriented PBCO growth. We explain that the c-axis oriented growth is the result of the growth of the PBCO (019) planes on the LSGO (101) planes. We conclude that the nucleation and growth of the PBCO films at the initial stages depends on the crystallographic plane of the substrate surfaces, however, as the film grows further, the kinetics of the deposition process favors b-axis oriented growth.

Keywords

References

  1. Science v.249 Epitaxial and smooth films of a-axis $YBa_2Cu_3O_7$ Eom, C.B.;Marshall, A.F.;Laderman, S.S.;Jacowitz, R.D.;Geballe, T.H.
  2. Appl. Phys. Lett. v.57 no.10 Structural perfection of Y-Ba-Cu-O thin films controlled by the growth mechanism Ramesh, R.;Chang, C.C.;Ravi, T.S.;Hwang, D.M.;Inam, A.;Xi, X.X.;Li, Q.;Wu, X.D.;Venkatesan, T.
  3. Solid State Comm. v.69 no.3 Control of growth direction of epitaxial YBaCuO thin films on $SrTiO_3$ substrates Linker, G.;Xi, X.X.;Meyer, O,;Li, Q.;Geerk, J.
  4. Physica C v.246 High-rate growth of purely a-axis oriented YBCO high-Tc thin films by photo-assisted MOCVD Zhong, Q.;Chou, P.C.;Li, Q. L.;Taraldsen, G.S.;Ignatiev, A.
  5. Appl. Phys. Lett. v.57 no.23 a-axis oriented epitaxial $YBa_2Cu_3O_{7-x}-PrBa_2Cu_3O_{7-y}$ heterostructure Inam, A.;Rogers, C.T.;Ramesh, R.;Remsching, K.;Farrow, L.;Hart, D.;Venkatesan, T.;Wilkens, B.
  6. Appl. Phys. Lett. v.63 no.11 a-axis oriented epitaxial $YBa_2Cu_3O_{7-y}/PrBa_2Cu_{3-x}NbxO_{7-z}$ multistructures Hontsu, S.;Mukai, N.;Ishii, J.;Kawai, T.;Kawai, S.
  7. Mat. Res. Soc. Sym. Proc. v.341 Epitaxial relationships of the a-axis oriented $YBa_2Cu_3O_{7-x}$ thin films on the $PrBa_2Cu_3O_{7-x}$ buffered $SrTiO_3$ (100) by two step PLD Sung, G.Y.;Suh, J.D.;Nahm, S.
  8. Physica C v.170 Microstructure studies of a-axis oriented $YBa_2Cu_3O_{7-x}-PrBa_2Cu_3O_{7-y}$ heterostructure Ramesh, R.;Inam, A.;Hart, D.L.;Rogers, C.T.
  9. Physica C v.252 Thickness dependence of resistance-temperature characteristics of c-axis and a-axis oriented $YBa_2Cu_3O_{7-x}$ ultra thin films Suh, J.D.;Sung, G.Y.
  10. Appl. Phys. Lett. v.61 no.9 a-axis oriented growth of $YBa_2Cu_3O_{7-y}$ films on $LaSrGaO_4$ (100) substrates Hontsu, S.;Mukai, N.;Ishii, J.;Kawai, T.;Kawai, S.
  11. Appl. Phys. Lett. v.63 no.7 In-plane alignment of a-axis oriented $YBa_2Cu_3O_{7-x}$ thin films Mukaida, M.;Miyazawa, S.
  12. Phy. Rev. B v.48 no.14 Anisotropic transport properties of in-plane-aligned a-axis $YBa_2Cu_3O_7$ thin films Suzuki, Y.;Lew, D.;Marshall, A.F.;Beasley, M.R.;Geballe, T.H.
  13. Appl. Phys. Lett. v.67 no.8 Superconducting and structural properties of in-plane aligned a-axis oriented $YBa_2Cu_3O_{7-x}$ thin films Sung, G.Y.;Suh, J.D.
  14. Appl. Phys. Lett. v.64 no.16 Atomic graphoepitaxy: A growth model for c-axis in-plane-aligned, a-axis oriented $YBa_2Cu_3O_x$ thin films Miyazawa, S.;Mukaida, M.
  15. Appl. Phys. Lett. v.65 no.24 Growth and superconductivity of c-axis in-plane aligned in-planealigned $YBa_2Cu_3O_x$ films fabricated by the selftemplate method Mahajan, S.;Wen, J.G.;Ito, W.;Yoshida, Y.;Kubota, N.;Liu, C.J.;Morishita, T.
  16. Phy. Rev. B v.47 no.17 Nucleation and growth mechanisms of a,b-axis oriented $YBa_2Cu_3O_x$ films on $LaAlO_3$ Streiffer, S.K.;Lairson, B.M.;Zielinski, E.M.;Bravman, J.C.
  17. Appl. Phys. Lett. v.55 no.22 Observation of the early stages of growth of superconducting thin films by transmission electron microscopy Norton, M.G.;Tietz, L.A.;Sommerfelt, S.R.;Carter, C.B.
  18. Physica C v.202 Growth and relaxation mechanisms of $YBa_2Cu_3O_x$ films Pennycook, S.J.;Chisholm, M.F.;Jesson, D.E.;Feenstra, R.;Zhu, S.;Zheng, X.Y.;Lowndes, D.J.