Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Bromination of Alkyl Chlorides by LiBr and CaBr2 adsorbed on Alumina

LiBr와 CaBr2가 흡착된 알루미나상에서 일어나는 염화 알킬의 브롬화반응

  • Received : 1996.04.17
  • Accepted : 1996.07.16
  • Published : 1996.10.10
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Abstract

Several alkyl chlorides were brominated using LiBr and $CaBr_2$ adsorbed on alumina in the absence of solvent. The yields of alkyl bromides were fairly high. Such a high reactivity by these bromide salts might be due to the interaction of minute amount of water and the salt on alumina. Differential scanning calorimetry (DSC) thermogram was provided and discussed.

알루미나에 LiBr와 $CaBr_2$를 각각 흡착시켜 용매가 없는 상태에서 여러 가지 염화 알킬과 반응시켜 좋은 수득률로 해당하는 브롬화 생성물을 얻을 수 있었다. 이러한 높은 반응성은 알루미나에 흡착되어 있는 극소량의 물과 브롬화 금속간의 상호작용이 알루미나 상에서 일어날 수 있기 때문이라는 것을 Differential scanning calorimetry (DSC) 열분석 실험과 문헌을 통하여 고찰하였다.

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