Physico-Chemical Properties among Three Products of Granular Fused Magnesium Phosphate

세가지 입상(粒狀) 용성인비(熔成燐肥) 제품간(製品間)의 이화학적(理化學的) 특성(特性)

  • Lim, Dong-Kyu (National Yeongnam Agricultural Experiment Station, RDA) ;
  • Kim, Seok-Cheol (National Agricultural Sciences and Technology Institute, RDA) ;
  • Lee, Sang-Kyu (National Agricultural Sciences and Technology Institute, RDA) ;
  • Choi, Du-Hoi (National Yeongnam Agricultural Experiment Station, RDA) ;
  • Kang, Ui-Gum (National Yeongnam Agricultural Experiment Station, RDA) ;
  • Park, Kyeong-Bae (National Yeongnam Agricultural Experiment Station, RDA)
  • Published : 1996.06.30

Abstract

This experiment was carried out to compare with the physico-chemical properties of granular fused magnesium phosphates which were two domestic products(Pungnong Biryo Industrial Co., LTD and Kyunggi Chemical Industrial Co., LTD) and a imported Chinese product. The changes of pH, distribution of particle size, disintegration in water and in soil, hardness in soil, chemical composition, and dissolution rates in water, in soil and in 2% citric acid solution were investigated. The changes in pH were bigger in Jungmun series(black volcanic soil), in the imported chinese product, and in Jungmun series with the larger quantities applied. The domestic products were lower in pH, calcium, alkalinity and 1/2N-HCl soluble silicate than the Chinese product but total(Aqua regia) soluble phosphate, 2% citric acid soluble phosphate, 1/2N-HCl soluble and 2% citric acid soluble magnesium, and 2% citric acid soluble manganese concentration were similar among the domestic products and the imported product. In particle sizes, Chinese product was the biggest, Kyunggi product was the next, and Pungnong product was the smallest. The changes of disintegration rate in water and in soil were smaller in Pungnong and Kyunggi products at the early days of dissolution, and there were decreased with the order of Kyunggi product> Chinese product> Pungnong product at the latter days. The hardness of the products in soil was the strongest in Kyunggi product, the next was Pungnong product and Chinese product was the weakest so as to hardly measurable. The changing dissolution rates of 2% citric acid soluble phosphate concentration of granular fused magnesium phosphate products were the highest in Kyunggi product and the lowest in Pungnong product at the early days, the three products were dissolved over 90% within 50 days, and there were no clear difference among the products after 70 days of dissolution. The dissolution rates of 2% citric acid soluble phosphate concentration of granular fused magnesium phosphate products in soil were the highest in Pungnong product and Chinese product was the lowest, but they were less than 60% in 100 days of dissolution.

국내산(國內産)과 수입(輸入) 중국산(中國産) 입상(粒狀) 용성인비(熔成燐肥)의 물리화학적 특성을 비교하기 위해 pH의 경시적 변화, 입도분포(粒度分布), 수중 및 토양중 붕괴도(崩壞度), 토양중 경도(硬度), 제품의 화학성분(化學成分) 함량(含量) 분석(分析), 수중 및 토양중 구용성(枸溶性) 인산(燐酸) 용출율(溶出率) 등(等)을 검토한 결과를 요약(要約)하면 다음과 같다. 1. pH의 경시적(傾時的) 변화(變化)는 중문통(中文統)(농암갈색(濃暗褐色) 토양(土壤))이 평대통(坪垈統)(흑색(黑色) 토양(土壤))보다, 수입(輸入) 중국산(中國産) 제품(製品)이 풍농비료 제품 보다, 중문통(中文統)에 용성인비(熔成燐肥)를 다량(多量) 시용(施用)한 것이 소량 시용한 것 보다 pH의 변화(變化)가 컸었다. 2. 국내산(國內産) 용성인비(熔成燐肥)는 수입 중국산 용성인비에 비하여 pH, 석회(石灰), 알카리분 및 가용성(可溶性) 규산함량(珪酸含量)이 낮았으나 인산(燐酸) 전량(全量), 구용성(枸溶性) 인산(燐酸), 고토(苦土)(가용성(可溶性) 구용성(枸溶性)) 및 구용성(枸溶性) 망간은 약간 높거나 서로 비슷하였다. 3. 입도(粒度)의 크기는 수입(輸入) 중국산(中國産) 제품(製品)이 가장 크고 그 다음이 경기화학(京畿化學) 제품(製品)이며 풍농비료(豊農肥料)의 제품(製品)은 비교적 입자가 작았다. 4. 수중(水中) 및 토양중(土壤中) 붕괴도(崩壞度)는 초기(初期)에는 풍농비료 제품과 경기화학 제품이 낮았으나 후기(後期)에는 경기화학 제품>수입 중국산 제품>풍농비료 제품의 순으로 붕괴도가 낮았다. 5. 토양중(土壤中) 경도(硬度)는 경기화학(京畿化學) 제품(製品)이 가장 단단하였고 그 다음이 풍농비료(豊農肥料) 제품(製品)이며 수입(輸入) 중국산(中國産) 제품(製品)은 경도계로 측정할 수 없을 정도로 약하였다. 6. 구용성(枸溶性) 인산(燐酸) 용출율(溶出率)은 초기에는 경기화학(京畿化學) 제품(製品)이 가장 높았고 풍농비료(豊農肥料) 제품(製品)은 가장 낮았으며, 용출 50일에는 3제품(製品) 모두 90% 이상 용출되었고 용출 70일 이후는 제품간(製品間) 차이가 거의 없었다. 7. 토양중(土壤中) 구용성(枸溶性) 인산(燐酸) 용출율(溶出率)은 풍농비료(豊農肥料) 제품(製品)이 가장 높았고 수입(輸入) 중국산(中國産) 제품(製品)이 가장 낮았으며 용출일 100일에도 60%를 넘지 못하였다.

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