Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Transfer of Electronic Excitation Energy in Poltstyrene Films Doped with an Intramolecular Proton Transfer Compound

  • Published : 1996.07.20
Download PDF
⟨ Previous Next ⟩

Abstract

The transfer of excitation energy from solvent to solute in polystyrene films doped with 2-(2'-hydroxyphenyl)benzothiazole (HBT) which undergoes intramolecular proton transfer in excited electronic state has been studied by employing steady state and time-resolved fluorescence measurements. The degree of Forster overlap between donor and acceptor molecule in this system is estimated to be moderate. Energy transfer efficiency increases with solute concentration at low concentration range and levels off at high concentration. It is observed that the excimer form of polystyrene is largely involved in energy transfer process. Photostability of HBT in polystyrene to UV light is also investigated to get insight into the long wavelength absorption band of HBT which was observed upon electron radiation.

Keywords

References

  1. J. Phys. Chem. v.94 Yamazaki, I.;Tamai, N.;Yamazaki, T.
  2. Ann. Rev. Biochem. v.47 Stryer, L.
  3. J. Photoscience v.1 Kim, H.;Kang, T. J.
  4. Synthetic Metals v.41-43 Bradley, D. D. C.;Brown, A. R.;Burns, P. L.;Burroughes, J. H.;Friend, R. H.;Holmes, A. B.;Mackay, K. D.;Marks, R. N.
  5. Disc. Faraday Soc. v.9 Kasha, M.
  6. The Theory and Practice of Scintillation Counting Birks, J. B.
  7. Organic Scintillators and Liquid Scintillation Counting Birks, J. B.;Horrocks, D. L.(ed.);Peng, C. T.(ed.)
  8. Applications of Liquid Scintillation Counting Horrocks, D. L.
  9. Nucl. Instr. Meth. in Phys. Res. v.A235 Renschler, C. L.;Harrah, L. A.
  10. Anal. Chem. Acta v.52 Kirkbright, G. F.;Narayanqswarmy, R.;West, T. S.
  11. J. Am. Chem. Soc. v.112 Catalan, J.
  12. J. Phys. Chem. v.90 Chou, P.;Aartsma, T. J.
  13. J. Phys. Chem. v.95 Parthenopoulos, D. A.;McMorrow, D.;Kasha, M.
  14. Appl. Spectroscopy v.45 D'ambrosio, C.;Leutz, H.;Taufer, M.;Gusten, H.
  15. J. Phys. Chem. v.95 Frey, W.;Laermer, F.;Elsaesser, T.
  16. Chem. Phys. Lett. v.148 Laermer, F.;Elsaesser, T.;Kaiser, W.
  17. Radiat. Phys. Chem. v.41 Bross, A. D.;Pla-Dalmau A.;Spangler, C. W.
  18. Standardization in Spectrophotometry and Luminescence Measurements, National Bureau of Standards Special Publication 466 Drexhage, K. H.;Mielenz, K. D.(ed.);Velapoldi, R. A.(ed.);Mavrodineanu, R.(ed.)
  19. J. Phys. Chem. v.91 Becker, R. S.;Lenoble, C.;Zein, A.
  20. J. Am. Chem. Soc. v.107 Itoh, M.;Fujiwara, Y.
  21. Z. Naturforsch. A. v.4 Forster, Th.
  22. Disc. Faraday Soc. v.27 Forster, Th.
  23. Proc. Phys. Soc. LXIX Cohen, S. G.;Weinreb, A.
  24. J. Chem. Phys. v.33 Berlman, I. B.
  25. J. Chem. Phys. v.36 Basile, L. J.
  26. J. Chem. Phys. v.43 Vala Jr., M. T.;Haebig, J.;Rice, S. A.
  27. Biochemistry v.19 Berman, H. A.;Yguerabide, J.;Taylor, P.
  28. Handbook of Polymer Science and Technology v.1 Torikai, A.;Cheremisinoff, N. P.(ed.)
  29. Handbook of Polymer Science and Technology v.1 Tanigaki, K.;Tateishi, K.
  30. Polym. Degrad. Stab. v.17 Torikai, A.;Kato, S.;Fueki, K.
  31. J. Phys. Chem. v.94 Brewer, W. E.;Martinez, M. L.;Chou, P.-T.