Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Effect of Transition Metal(II)-N,N-Bis(salicylaldehyde)phenylenediimines on the Electrochemical Reduction of Thionyl Chloride

  • Published : 1996.03.20
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Abstract

Catalytic effects of transition metal (Co2+, Ni2+) complexes of N,N-bis(salicylaldehyde)-o-phenylenediimine (SOPD), N,N-bis(salicylaldehyde)-m-phenylenediimine (SMPD), and N,N-bis(salicylaldehyde)-p-phenylenediimine (SPPD), on the reduction of thionyl chloride at glassy carbon electrode, are evaluated by determining the kinetic parameters with cyclic voltammetric technique. The charge transfer process for the reduction of thionyl chloride is strongly affected by the concentration of the catalysts. Some quadridentate Schiff base-M(Ⅱ) complexes show sizable catalytic activities for the reduction of thionyl chloride. Catalytic effects of [M(Ⅱ)(SOPD)] complexes are slightly larger compared to [M(Ⅱ)2(SMPD)2] and [M(Ⅱ)2(SPPD)2] complexes. On those electrodes deposited with the catalysts, the observed exchange rate constants (ko) are in the range of 0.89-2.28 × 10-7 cm/s, while it is 1.24 × 10-7 cm/s on the bare glassy carbon electrode.

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References

  1. J. Electrochem. Soc. v.126 Schlaikjer, C. R.;Goedel, F.;Marincic, N.
  2. J. Electrochem. Soc. v.126 Bowden, W.;Dey, A. N.
  3. Lithium Battery Technologyl Salmon, D. J.;Adamczyk, M. E.;Hendricks, L. L.;Abels, L. L.;Hal l, J. C.;Venkatasetty, H. (ed.)
  4. Soviet Electrochem. v.17 Kolomoets, A. M.;Pleshakov, M. S.;Dudnikov, V. I.
  5. J. Electrochem. Soc. v.129 Istone, W. K.;Brodd, R. J.
  6. Proc. 30th Power Sources Symp. Doddapaneni, N.
  7. J. Electrochem. Soc. v.131 Istone, W. K.;Brodd, R. J.
  8. J. Electrochem. Soc. v.131 Madou, M. J.;Szpak, S.
  9. J. Electrochem. Soc. v.134 Madou, M. J.;Smith, J. J.;Szpak, S.
  10. J. Power Sources v.21 Chiu, J. G.;Wang, Y. Y.;Wany, C. C.
  11. Proc. 27th Power Sources Symp. Behl, K.
  12. J. Power Sources v.24 Hagan, W. P.;Hampson, N. A.;Packer, R. K.
  13. J. Power Sources v.24 Hills, A. J.;Hampson, N. A.
  14. J. Elect rochem. Soc. v.136 Mosier-Boss, P. A.;Szpak, S.;Smith, J. J.;Nowak, R. J.
  15. J. Power Sources v.26 Bagotsky, V. S.;Kazarinov, V. E.;Volfkovich, Yu. M.;Kanevsky, L . S.;Beketayeva, L. A.
  16. J. Power Sources v.26 Hu, H. Y.;Ko, S. W.
  17. J. Power Sources v.26 Schlaikjer, K. R.
  18. J. Electrochem. Soc. v.140 Choi, Y. K.;Kim, B. S.;Park, S. M.
  19. Proc. 30th Power Symp. Doddapaneni, N.
  20. Proc. 31th Power Symp. Doddapaneni, N.
  21. Proc. Electrochem. Soc. v.82-1 Doddapaneni, N.
  22. Proc. Electrochem. Soc. v.86-12 Doddapaneni, N.
  23. Proc. 32nd Power Symp. Doddapaneni, N.
  24. Bull. Korean Chem. Soc. v.15 Kim, W. S.;Choi, Y. K.;Chjo, K. H.
  25. J. Electrochem. Soc. v.125 Dey, A. N.;Bro, P.
  26. J. Chem. Soc. Dalton Trans. Ashmawy, F. M.;Issa, R. M.;Amer, S. A.
  27. Inorg. Chem. v.15 Boucher, L. J.
  28. J. Phy. Chem. v.60 Ueno, K.;Martell, A. E.
  29. J. Power Sources v.36 Baturina, O. A.;Kanevsky, L. S.;Bagotzky, V. S.;Volod,ko, V. V.;Karasev, A. L.;Revina, A. A.
  30. Electrochemical methods Bard, A. J.;Faulkner, L. R.