통전 활성 연소에 의한 ${Ti}_{5}{Si}_{3}$${Ti}_{5}{Si}_{3}-{ZrO}_{2}$복합재료 합성

Electric Field-activated Self-propagating Synthesis of ${Ti}_{5}{Si}_{3}$ and ${Ti}_{5}{Si}_{3}-{ZrO}_{2}$ Composites

  • Son, In-Jin (Department of Materials Engineering, Chonbuk National University) ;
  • Go, In-Yong (Department of Metallurgical Engineering Chonbuk National University)
  • 발행 : 1996.07.01

초록

${Ti}_{5}{Si}_{3}$${Ti}_{5}{Si}_{3}-{ZrO}_{2}$ 복합재료의 연소합성에 미치는 전기장의 영향에 관하여 연구하였다. 45mole% 이상 첨가한 ${Ti}_{5}{Si}_{3}-{ZrO}_{2}$ 복합재료는 전기장하에서만 연소합성할 수 있었다. ${Ti}_{5}{Si}_{3}$-45mole% ${ZrO}_{2}$와 Ti5Si3-60mole% ${ZrO}_{2}$ 복합재료는 전기장을 가하지 않은 상태에서는 불안정한 연소파가 전파되었지만 반응은 완전히 일어나지 않았다 즉, 불안정한 연소파는 시편의 중앙 부근까지 전파 된 후 멈추었다. ${Ti}_{5}{Si}_{3}$-ZrO2 복합재료의 연소파 속도는 시편에 가해준 전기장에 의해 약간 증가하였다.

The influence of an electric field on the combustion synthesis of ${Ti}_{5}{Si}_{3}$-x ${ZrO}_{2)$(0 $\leq$ x $\leq$0.6)was investigated. Composite of X $\geq$0.45 can only be synthesized in the presence of an electric field. Although in the absence of an electri field the system with x = 0.45 and x=0.6 can sustain a nonsteady combustion wave, the reaction is not complete. That is, an unstable wave propagates to the middle of the sample and them becomes extinguished. Wave velocity o the ${Ti}_{5}{Si}_{3}-{ZrO}_{2}$ Composites slightly increases with the imposition of external field across the sample.

키워드

참고문헌

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