이량체액정의 PVT측정과 상전이 거동

PVT Measurement and Phase Transition Behavior of Dimer Liquid Crystals

N-substituted acrylamide hydrogel is reported to have the feature of bing transparent and sensitive enough to response to a temperature stimulus below the temperature of phase transition. Especially at the near of 35 C it becomes shrunk and opaque very quickly. It has also the characteristic of reversing swelling and shrinking. The experiment showed that it is possible to produce a functional gel of super water absorption with the process of free radical polymerizing PVA(polyvinylalcohol) and PAA(polyacrylamide), and crosslinking. The ratio of shrinking and swelling caused by copolymerization rises 10% to 80% at the each temperature of 20 C, 30 C, 40 C, respectively. Phase transition temperature of this gel by copolymerization is50 C while that of ordinary N-substituted acrylamides is between 32~35 C. This temperature reaches the rearing limit of animals and plants so that volumetric transition polymer gel can be ulilized in varying fields such as agriculture/gardening which are water-using field, on-off switch sensing temperature and volumetric variation, processing of liquid wastes and civil engineering works, architecture and electronics. We have no doubt that this material will be the high-functional resin in the hi-tech age of the near future.