Alkaline Hydrolysis of Polyester/Acetate Union Fabric

폴리에스테르/아세테이트 혼용직물의 알칼리 가수분해

  • Ju, Young Min (Dept. of Textile Eng., Chungnam National Univ, Taejon, Korea) ;
  • Kim, Myung Kyoon (Dept. of Textile Eng., Chungnam National Univ, Taejon, Korea) ;
  • Ahn, Kyoung Ryoul (Dept. of Textile Eng., Chungnam National Univ, Taejon, Korea) ;
  • Lee, Jeong Min (Dept. of Textile Eng., Chungnam National Univ, Taejon, Korea)
  • Published : 1996.11.01

Abstract

Alkaline hydrolysis to improve the hand of PET/acetate union fabric was studied in relation to skin saponification and retarding effect of salts on the alkaline hydrolysis of cellulose acetate fiber, accelerating effect of salts on the alkaline hydrolysis of PET fiber, and changes of total hand value(T.H.V) of PET/acetate union fabric treated with alkali/salt solution. It was found that the rate of saponification of acetate was delayed by the addition of salts such as LiCl, NaCl and CH$_{3}$COONa into NaOH solution below 10 minutes. The rate of shrinkage of acetate fabric treated with 5g/l NaOH solution at 9$0^{\circ}C$ and 60 minutes showed 20 % but it was decreased 8% by. the addition of 120g/l Concentration of inorganic salts. We could know that the rate of alkaline hydrolysis of filament yarn treated with alkali solution at 9$0^{\circ}C$ and 60 minutes was delayed about 3 % using 2,000T/M of hard twist yarn, especially acetate filament treated with alkali solution at 9$0^{\circ}C$ and 10 minutes was delayed about 10%. T.H.V. of PET/acetate union fabric was increased from 2.77 to 3.04~3.18 by the addition of salts into alkali solution.

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References

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