Synthesis and Characterization of the New Functional Polymer ―Synthesis of Polymer Containing Phosphorus―

새로운 기능성 고분자의 합성 및 그 특성에 관한 연구(I) ―인 함유 고분자의 합성―

  • Moon, Byeong Hwa (Dpt. of Textile Engineering, Yeungnam University, Kyeongsan 712-749, Korea) ;
  • Son, Tae Won (Dpt. of Textile Engineering, Yeungnam University, Kyeongsan 712-749, Korea) ;
  • Lim, Sang Kyn (Dpt. of Textile Engineering, Yeungnam University, Kyeongsan 712-749, Korea) ;
  • Koo, Kang (Dpt. of Textile Engineering, Yeungnam University, Kyeongsan 712-749, Korea)
  • 발행 : 1996.11.01

초록

Poly(4-morphonylphosphonate of bisphenol A) (PMPB) was synthesized by the interfacial polymerization of phosphonic dichloride, 4-morphonyl (PDCM) and bisphenol A in an aqueous-organic biphasic system. Synthesized polymer was found to be PMPB by using EA, FT-IR and $^{1}$H-NMR. Prepared PMPB had different values of molecular weight depending on the solubility in the organic phase: the higher the solubility, the higher the molecular weight. PMPB is amorphous and its thermal decomposition temperature is about 35$0^{\circ}C$. PMPB is congenial to application to polypropylene by blending because of no reaction with polypropylene.

키워드

참고문헌

  1. J. Appl. Polym. Sci v.24 no.249 N. Inagaki;K. Katsura
  2. Flame Retardant Polymeric Materials v.1 M. Lewin;S. M. Atlas;E. M. Pearce
  3. Text. Chem. Colar v.10 no.79 G. J. Leitner;W. L. Coble
  4. 特公(日本) 昭44-156399 福田建詰厚夫
  5. U. S. Pat. 3,526613
  6. Text. Res. J. v.41 J. Dipietro;Stepniczka;R. C. Nametz
  7. J. Appl. Polym. Sci. v.17 J. E. Bostic;K. N. Yen;R. H. Baker
  8. The Aldrich Library of NMR Spectra v.Ⅹ C. J. Pouchert;J. R. Campbell
  9. Properties of Polymers D. W. Van Krevelen
  10. Properties of Polymers(3rd ed.) Elsevier