Effects of Substrate Temperature and the $O_2$/Ar Ratio on the Characteristics of RF Magnetron Sputtered $RuO_2$ Thin Films

  • 발행 : 1996.03.01

초록

$RuO_2$ thin films deposited directly on Si substrate by RF magnetron sputtering method using $RuO_2$ target have been investigated. Special interest was focused on the effect of process parameter on the surface roughness of $RuO_2$ films. Crystallization behavior and electrical properties of the films deposited at $300^{\circ}C$ were superior to those deposited at room temperature. Metallic Ru phase was formed in pure Ar and this phase had resulted poor adhesion after post annealing process in oxidizing ambient. Microstructural analysis reveals that the size of the $RuO_2$ crystallites gets smaller and the surface becomes smoother as the $O_2$ partial pressure or film thickness decreases. Irrespective of the $O_2/Ar$ ratio, resistivity of $RuO_2$ films ranged in $50~70 {\mu}{\Omega}-cm$. As the film thickness decreases, there is a thickness where the resistivity rises abruptly. Such an onset thickness turned out to be dependent n the $O_2$/Ar ratio.

키워드

참고문헌

  1. 4th International Symposium on Intergrated Ferroelectrics v.2 Bottom Electrodes for Ferroelectric Thin Films H. N. Al-Shareef;K. D. Fifford;P. D. Hren;S. H. Rou;O. Auciello;A. I. Kingon
  2. J. Electrochem. Soc. Solid-State Science and Technology v.132 Conducting Transition Metal Oxides; Possibility for RuO₂ in VLSI Metallization L. Krusin-Elbaum;M. Wittmer
  3. J. Electrochem. Soc. Solid-State Science and Technology v.126 no.11 Ru and RuO₂ as Electrical Contact Materials: Preparation and Environmental Interactions R. G. Vadimsky;R. P. Frankenthal;D. E. Thompson
  4. J. Mater. Res. v.9 no.11 Reactive Ion Etching of $PbZr_{1-x} Ti_x O_3$ and RuO₂ Films by Environmentally Safe Gases W. Pan;S. B. Desu;In K.
  5. J. Electrochem. Soc. v.140 no.9 Electrode for PbZr,$Ti_{1-x} O_3$ Perroelectric Thin Films D. P. Vijay;S. B. Desu
  6. Appls. Phys. Lett. v.64 no.22 High Dielectric Constant (Ba,Sr)TiO₃ Thin Films Prepared on RuO₂/sapphire K. Takemura;T. Sakuma;Y. Miyasaka
  7. Jpn, J. Appl. Phys. v.33 no.9B Preparation and Properties of Ru and RuO₂ Thin Film Electrodes for Ferroelectric Thin Films H. Maiwa;N. Ichinose;K. Okazaki
  8. Appl. Phys. Lett. v.50 no.26 Characterization of Reactively Sputtered Ruthenium Dioxide for Very Large Scale Intgrated Metallization L. Krusin-Elbaum;M. Wittmer;D. S. Yee
  9. Intergrated Ferroelectrics v.2 Bottom Electrodes for Integrated Pb(Zr,Ti)O₃ Films P. D. Hren;S. H. Rou;H. N. Al-Shareef;M. S. Ameen;O. Auciello;A. I. Kingon
  10. J. Mater. Res. v.8 no.1 Fatique of Ferroelectric $PbZr_x Ti_y O_3$ Capacitors with Ru and $RuO_x$ Electrodes S. D. Bernstein;T. Y. Wong;Y. Kisler;R. W. Tustison
  11. Physical Review B. v.13 no.b Electronic Structure of RuO₂OsO₂ and IrO₂ L. F. Mattheiss