Preparation of Cellulose Graft Copolymers as Super Water Absorbents(II)-Water and Moisture Sorptive Properties of Super Water Absorbents Prepared from Low Cyanoethylated Wood Pulp-g-PAM-

고흡수성 재료로서 셀룰로오스계 그라프트 고분자의 제조(II) - 저치환 시아노에틸화 목재 펄프-g-PAM으로부터 제조한 고흡수성 고분자의 흡수 및 흡습성 -

  • 김재필 (전북대학교 농과대학 임산공학과) ;
  • 문성필 (전북대학교 농과대학 임산공학과, 임업연구원 남부임업시험장, 전북대학교 공과대학 고분자공학과)
  • Published : 1996.08.01

Abstract

The water and moisture sorptive properties of the super water absorbents(H-LCE-WP-g-PAM) prepared from low cyanoethylated wood pulp(LCE-WP) were investigated. The H-LCE-WP-g-PAM showed remarkably higher equilibrium water absorbency than a commercial absorbent, although the latter absorbed water more rapidly. The absorbency of H-LCE-WP-g-PAM in bivalent salt solutions was lower than that in monovalent salt solution of same concentration. Phase transitions of the H-LCE-WP-g-PAM were not detected clearly in methanol/water mixtures of various composition. The absorbency of H-LCE-WP-g-PAM was highly dependent on the pH of the solution. H-LCE-WP-g-PAM exhibited the maximum absorbency at pH 7, and it decreased sharply with increasing of acidity and basicity. On the other hand, temperature dependence of the absorbency was not noticeable in the range of 5~8$0^{\circ}C$ tested in this study. H-LCE-WP-g-PAM absorbed moisture fast in the early stage.

Keywords

References

  1. 목재공학 v.22 박상범
  2. Principles of Polymer Chemistry P. J. Flory
  3. 한국섬유공학회지 v.31 김정현;송경근;윤기종
  4. Sen-I Gakkaishi v.49 M. Yoshinobu;M. Morita;M. Higuchi;I. Sakata
  5. Sen-I Gakkaishi v.46 N. Miyata;I. Sakata
  6. 한국섬유공학회지 v.31 송경근;윤기종;고석원
  7. 폴리머 v.9 심정섭;장정식
  8. Sen-I Gakkaishi v.47 M. Yoshinobu;M. Morita;I. Sakata
  9. Sen-I Gakkaishi v.42 M. Ohguchi
  10. Sen-I Gakkaishi v.45 M. Ohguchi;M. Saitoh
  11. 한국섬유공학회지 v.31 송경근;윤기종;고석원
  12. Polymer Bulletin v.5 B. Ranby;C. Rodehed
  13. Mokuzai Gakkaishi v.37 S. B. Park;M. Morita;I. Sakata
  14. 한국섬유공학회지 v.33 문성필;김재필;吉延匡弘;森田光傳
  15. 목재과학실험서 박상진 외 3인
  16. Sen-I Gakkaishi v.47 N. Miyata;I. Sakata
  17. J. Korea Tappi v.25 S. B. Park;M. Morita;I. Sakata