Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

A Study of Fiber Formation and Physical Properties of Polyacrylonitrile Copolymer with Pyrrolidone Group

피롤리돈기를 가진 폴리아크릴로니트릴 공중합체의 섬유제조 및 그 물성

  • Lee, Sin-Hui (Technical R&D Center, Hanil Synthetic Fiber Co., Ltd.) ;
  • Kim, Hong-Seong (Dept. of Silk Textile, Miryang National Univ.)
  • 이신희 ((주)한일합섬 기술연구소) ;
  • 김홍성 (밀양산업대학교 이공학부 견섬유학과)
  • Published : 1996.05.01

⟨ Previous Next ⟩

Abstract

To improve the static electricity of acrylic fiber, chemical method was introduced. Polyacrylonitrile copolymer with pyrrolidone group(PBPGP) was synthesized by copolymerization of acrylonitrile(AN) and methylacrylate(MA) initiated by aqueous sulfite-chlorate redox system under the presence of polyvinylpyrrolidone(PVP). The fibers from PBPGP and virgin acryl polymer(PAN) were manufactured by wet-spinning at DMF system. The physical properties of fibers were investigated by IR, SEM, DSC, Rheovibron, Instron and Static Honestometer. Within measured range the physical properties of PBPGP and PAN fibers were nearly on a par except static the electricity the electricfied potential of PBPGP fiber differ little from that of PAN fiber but the half-life of static electricity of PBPGP fiber was markedly shorter than that of PAN fiber.

Keywords

References

  1. Encyclopedia of Polymer Science and Technology v.1 N.M. Bikales(ed.)
  2. Man-Made Fibers(6th ed.) R.W. Moncrieff
  3. Handbook of Fiber Science and Technology v.4 B.G. Frushour;R.S. Knorr
  4. J. Korean Soc. Text. Eng. Chem. v.24 J.C. Lee;S.L. Yun
  5. J. Polym. Sci. v.31 W. Y. Chiang;C. C. Huang
  6. J. Appl. Polym. Sci. v.49 P. Bajaj;D. K. Paliwal;A. K. Gupta
  7. Gobunshi Ronbunshu v.36 R. Endo;H. Okano;A. Goto
  8. Text. Res. J. v.50 P. Bajaj;A.K. Sengupta;P.C. Jain
  9. Sen-i Gakkaishi v.32 T.N. Nakajima;J. Katano;E. Isobe
  10. Polymer Blends and Composites J.A. Manson;L.H. Sperling
  11. Polymer Blends and Composites in Multiphase Systems C.D. Han
  12. J. Appl. Polym. Sci. v.49 R.B. Mathur;J. Mittal;O.P. Bahl
  13. J. Appl. Polym. Sci. v.47 A. K. M. Asaduzzaman;H. Raval;S. Devi
  14. J. Appl. Polym. Sci. v.48 H. Kubota
  15. J. Korean Soc. Text. Eng. Chem. v.20 S.I. Hong
  16. Melliand Textilber. v.37 K. Neufang
  17. Melliand Textilber v.38 H. Rath;H. Rehm. H. Rummler;E. Specht
  18. Encyclopedia of Chemical Technology v.23 M. Grayson(ed.)
  19. Polymer-Polymer Miscibility O. Olabisi;L.M. Robeson;M.T. Shaw
  20. J. Koean Fiber Soc. v.31 H.S. Kim;E.J. Park;S.M. Park;Y.H. Bang;H.H. Cho
  21. Sen-i Gakkaishi v.33 C. Nakayama;K. Kamide;S. Manabe
  22. Sen-i Gakkaishi v.33 C. Nakayama;K. Kamide;S. Manabe
  23. Sen-i Gakkaishi v.33 C. Nakayama;K. Kamide;S. Manabe;T. Sakamoto