Preparation of Sophorose - I. Chemical Synthesis of Sophorose from D-Glucose

Anufriev, Victor P.;Park, Jong-Dae;Lee, You-Hui;Kim, Shin-Il;Baek, Nam-In;

Applied Biological Chemistry

Volume 39 Issue 6
/
Pages.512-516
/
1996
/
2468-0834(pISSN)
/
2468-0842(eISSN)

The Korean Society for Applied Biological Chemistry (한국응용생명화학회)

Preparation of Sophorose - I. Chemical Synthesis of Sophorose from D-Glucose

Sophorose의 제조-I. D-Glucose로부터 sophorose의 화학적 합성

Anufriev, Victor P. (Pacific Institute of Bioorganic Vladivostok) ;
Park, Jong-Dae (Korea Ginseng & Tobacco Research Institute) ;
Lee, You-Hui (Korea Ginseng & Tobacco Research Institute) ;
Kim, Shin-Il (Korea Ginseng & Tobacco Research Institute) ;
Baek, Nam-In (Kyung Hee University)

;
박종대 (한국인삼연초연구원) ;
이유희 (한국인삼연초연구원) ;
김신일 (한국인삼연초연구원) ;
백남인 (경희대학교)

Published : 1996.12.31

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Abstract

Sophorose $(2-O-{\beta}-D-glucopyranosyl-D-glucopyranose)$ was chemically synthesized from D-glucopyranose through six steps of chemical reactions with the yield of 21%. The chemical structures of sophorose and some compounds obtained during reactions were confirmed by interpretations of spectral data, NMR, IR, etc.

Sophorose $(2-O-{\beta}-glucopyranosyl-D-glucopyranose)$를 2분자의 D-glucopyranose로부터 6단계의 화학반응과정을 통하여 21%의 수율로 합성하는 방법을 확립하였다. Sophorose 및 얻어진 중간생성물들에 대하여 NMR, IR 등의 스펙트럼 데이타를 해석하여 구조를 확인하였다.

Keywords

유기합성;