Solidification and Phase Equilibria Studies by Directional Solidification Technique in the Ni-Al System

Ni-Al계에서 일방향응고에 의한 응고 및 상평형 연구

  • 이재현 (한국기계연구원 재료기술연구부) ;
  • 조창용 (한국기계연구원 재료기술연구부) ;
  • 이종훈 (한국기계연구원 재료기술연구부) ;
  • 최승주 (한국기계연구원 재료기술연구부)
  • Published : 1995.12.31

Abstract

The intermetallic compound $Ni_3Al$ causes a peritectic reaction at the composition and temperature very close to the eutectic reaction in Ni-Al system. Although the phase diagram accepted for this system by ASM Handbook has the eutectic forming between the $\gamma$ and $\gamma$ phases, directional solidification study has shown that the eutectic occurs between $\beta$ and $\gamma$. This work examines the liquidus region using quenched, directional solidification experiments that preserve the microstructrues formed at the solidification front. It is also shown that under certain composition and growth conditions a metastable eutectic between the $\beta$ and $\gamma$ phases forms in this system. Finding of the metastable eutectic provided an important information to understand the phase equilibria near the $Ni_3Al$ composition.

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