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A study on the Kinetics velocity for hydrolysis reaction of vanillylidene imine derivatives

Vanillylidene imine 유도체의 가수분해 반응에 관한 속도론적 연구

  • Sung, Ki-Chun (Dept. of chemical Engineering, Dae-Jin University) ;
  • Kim, Ki-Jun (Dept. of chemical Engineering, Dae-Jin University)
  • 성기천 (대진대학교 공과대학 화학 공학과) ;
  • 김기준 (대진대학교 공과대학 화학 공학과)
  • Published : 1995.11.30

Abstract

The Kinetics velocity for hydrolysis reaction of vanillylidene imine derivatives has been measured by ultra-violet ray spectrophotometer in 20wt% $dioxane-H_2O$ at $25^{\circ}C$. It was measured the reaction rate Constant of vanillylidene imine derivatives that can be applied widely following to pH-change at $25^{\circ}C$. Final products that hydrolyzed the vanillylidene imine certified in vanillin and aniline derivative, and the effect of substitution radical that has affected on hydrolysis reaction was largely promoted to reaction rate by electron attrating group in acidity and electron donoring group in basic. From the results of rate constant to hydrolysis reaction, substituent radical effect and final products. It has certified the hydrolysis reaction mechanism of vanillylidene imine derivatives.

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