한국응용과학기술학회지 (Journal of the Korean Applied Science and Technology)

  • 제12권1호
  • /
  • Pages.35-41
  • /
  • 1995
  • /
  • 1225-9098(pISSN)
  • /
  • 2288-1069(eISSN)
한국응용과학기술학회 (The Korean Society of Applied Science and Technology)
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Benzoyl Styrene 유도체의 가수분해 반응 메카니즘과 그 반응속도론적 연구

The Kinetics and Mechanism of the Hydrolysis to Benzoyl Styrene Derivatives

  • 이기창 (명지대학교 공과대학 화학공학과) ;
  • 윤철훈 (명지대학교 공과대학 화학공학과) ;
  • 황성규 (명지대학교 공과대학 화학공학과) ;
  • 오세영 (명지대학교 공과대학 화학공학과)
  • Lee, Ki-Chang (Dept. of Chemical Engineering, Myong Ji University) ;
  • Yoon, Chul-Hun (Dept. of Chemical Engineering, Myong Ji University) ;
  • Hwang, Sung-Kwy (Dept. of Chemical Engineering, Myong Ji University) ;
  • Oh, Se-Young (Dept. of Chemical Engineering, Myong Ji University)
  • 발행 : 1995.05.31
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초록

The Hydrolysis kinetics of Benzoyl Styrene Derivatives[I]${\sim}$[IV] was investigated by ultraviolet spectrophotometery in 5% dioxane-$H_2O$ at $40^{\circ}C$. The structure of these compounds were ascertained by means of ultraviolet, melting point, IR and NMR spectra. The rate equations which were applied over a wide pH range (pH $1.0{\sim}13.0$) were obtained. The substituent effects on Benzoyl styrene derivatives[I]${\sim}$[IV] were studied, and the hydrolysis were facilitated by electron attracting groups. On the basis of the rate equation and substitutent effect and final product, the plausible hydrolysis reaction mechanism was proposed: At pH 1.0${\sim}$pH 9.0, not relevant to the hydrogenl ion concentration, neutral $H_2O$ molecule competitively attacked on the double bond. By contrary. Above pH 9.0, It was proportional to concentration of hydroxidel ion.

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