Bulletin of the Korean Chemical Society

  • 제16권5호
  • /
  • Pages.439-443
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  • 1995
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Catalytic Asymmetric Allylic Alkylation with A Novel P-S Bidentate Ligand

  • 발행 : 19950500
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초록

Both enantiomers of (S)-(-)-2-(diphenylphosphino)-2'-mercapto-1,1'-binaphthyl and their derivatives were obtained by synthesis from racemic 2,2'-dihydroxy-1,1'-binaphthyl and subsequent resolution. The utilities of these ligands were investigated briefly. And among these, S-methyl derivative 15 has proved to be an effective ligand for Pd-catalyzed allylic alkylation.

키워드

참고문헌

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피인용 문헌

  1. ChemInform Abstract: Catalytic Asymmetric Allylic Alkylation with a Novel P-S Bidentate Ligand. vol.26, pp.46, 1995, https://doi.org/10.1002/chin.199546112
  2. Chiral Complexes of RhI Containing Binaphthalene-Core P,S-Heterobidentate Ligands − Synthesis, Characterization, and Catalytic Activity in Asymmetric Hydrogenation of α,β-U vol.2003, pp.3, 1995, https://doi.org/10.1002/ejic.200390077
  3. Binaphthalene-templated N,S- and N,P-heterobidentate ligands with an achiral oxazoline pendant : Synthesis and assessment in asymmetric catalysis vol.196, pp.1, 1995, https://doi.org/10.1016/s1381-1169(02)00632-5
  4. Thioether containing ligands for asymmetric allylic substitution reactions vol.10, pp.3, 2007, https://doi.org/10.1016/j.crci.2007.01.004
  5. Recent developments on chiral P,S-type ligands and their applications in asymmetric catalysis vol.46, pp.26, 1995, https://doi.org/10.1039/c000207k
  6. Atroposelective synthesis of axially chiral P,S-ligands based on arynes vol.2, pp.6, 1995, https://doi.org/10.1039/c5qo00067j
  7. Evolution of phosphorus-thioether ligands for asymmetric catalysis vol.56, pp.74, 1995, https://doi.org/10.1039/d0cc04145a