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Studies on the Macrocycle-mediated Transport of Divalent Metal Ions in a Supported Liquid Membrane System

  • 발행 : 19950100

초록

Macrocyclic ligands have been studied as cation carriers in a supported liquid membrane system. Cd2+ has been transported using nitrogen substituted macrocycles as carriers and several divalent metal ions (M2+=Zn, Co, Ni, Cu, Pb, Mg, Ca, and Sr) have been transported using DBN3O2, DBN2O2and PolyNtnoen as carriers in a supported liquid membrane system. Competitive Cd2+-M2+ transport studies have also been carried out with the same system. Ligand structure, stability constant, membrane solvent and carrier concentration are also important parameters in the transport of metal ions.

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참고문헌

  1. J. Am. Chem. Soc. v.107 Behr, J. P.;Lehn, J. M.
  2. J. Membr. Sci. v.10 Lonsdale, H. K.
  3. Bull. Korean Chem. Soc. v.9 Cho, M. H.;Seon Woo, K. H.;Heo, M. Y.;Lee, I. C.;Yoon, C. J.;Kim, S. J.
  4. Bull. Korean Chem. Soc. v.12 Cho, M. H.;Chun, H. S.;Kim, J. H.;Rhee, C. H.;Kim, S. J.
  5. J. Memb. Sci. v.2 Baker, R. W.;Tuttle, M. E.;Kelly, D. J.;Lonsdale, H. K.
  6. Sep. Sci. Technol. v.19 Danesi, P. R.
  7. J. Memb. Sci. v.14 Chiarizia, R.;Castagnola, A.;Danesi, P. R.;Horwiz, E. P.
  8. J. Am. Chem. Soc. v.102 Anderegg, G.;Ekstrom, A.;Lindoy, L. F.;Smith, R. J.
  9. J. Korean Chem. Soc. v.34 Kim, J. H.;Cho, M. W.;Hyeoun, D. H.;Park, H. B.;Kim, S. J.;Lee, I. C.