Polymeric Interactions of Dispersant and Binder in Aqueous Silicon Nitride Suspensions

질화규소 현탁액에서 분산제와 결합제의 상호작용연구

  • Kim, Bong-Ho (Dept. of Mater. Sci. and Eng., Changwon Nat. Univ) ;
  • Kim, Myong-Ho (Dept. of Mater. Sci. and Eng., Changwon Nat. Univ) ;
  • Lee, Soo (Dept. of Chem., Changwon Nat. Univ) ;
  • Paik, Un-Gyu (Dept. of Mater. Sci. and Eng., Changwon Nat. Univ)
  • Published : 1995.08.01

Abstract

In aqueous slurry processing of silicon nitride, the interaction of dispersant and binder used as polymeric processing additives on the silicon nitride particle surface was studied to identify the effect of these processing polymeric additives on the ceramic powder processing. The adsoprtion isotherm study of anionic organic molecule as dispersant and nonionic organic molecules as binder of silicon nitricde was studied to investigate the effect of these processing organic additives on the physicochemical properties of silicon nitride particles. As anionic molecule adsorbed onto silicon nitrice surface, the IEP of silicon nitride shifted toward acidic pH and changed the stability of silicon nitride particle. However, the adsorption of binder as nonionic organic molecule onto silicon nitride surface did not changed the IEP but caused the decrease of electrostatic potentials of silicon nitride. These distinctive adsorption behaviors of organic additives on silicon nitride particles can be closely correlated to the stability of silicon nitride particles suspended in aqueous media.

Keywords

References

  1. Introduction to the Principles of Ceramic Processing J.S. Reed
  2. Ceramics: Industrial Processing and Testing J.T. Jones;M.F. Berard
  3. J. Am. Ceram. Soc. v.73 no.7 Pressureless Sintering of SiC-Whisker-Reinforced Al₂O₃Composites: Ⅰ, Effect of Matrix Powder Surface Area H.W. Lee;M.D. Sacks
  4. Am. Ceram. Soc v.9 Microstructure Control Through Colloidal Consolidation in Advances in Ceramics, Formaing of Ceramics I.A. Aksay;J.A. Mangles(ed.)
  5. J. Am. Ceram. Soc. v.66 no.4 Role of Sodium Citrate in Aqueous Milling of Aluminum Oxide M.D. Sacks;T.Y. Tseng
  6. J. Am. Ceram. Soc. v.72 no.1 Powder Processing Science and Technology for Increased Reliability F.F. Lange
  7. J. Am. Ceram. Soc. v.11 no.2 Electrostatic and Sterical Stabilization of TiO₂Dispersions S.G.J. Heijman;H.N. Stein
  8. Coll. and Surf.: A v.95 no.1 Interparticle Forces Arising From Adsorbed Polyelectrolytes in Colloidal Suspensions Y.K. Leong;P.J. Scales;T.W. Healy;D.V. Boger
  9. J. Am. Ceram. Soc. v.78 no.1 Colloidal Stability and Titania Precipitate Morphology: Influence of Short-Range Repulsions J.L. Look;C.F. Zukoski
  10. J. Am. Ceram. Soc. v.78 no.4 Influence of Slurry Flocculation on the Character and Compaction of Spray-Dried Silicon Nitride Granules H. Takahashi;N. Shinohara;M. Okumiya;K. Uematsu;T. Junlchiro;Y. Iwamoto;H. Kamiya
  11. J. Fluid Mech. v.190 Electro-Acoustic Effects in a Dilute Suspension of Spherical Particles R.W. O'Brien
  12. Disc. Faraday Soc. v.90 Electroacoustic Studies of Moderately Concentrated Colloidal Suspensions R.W. O'Brien;B.R. Midmore;A. Lamb;R.J. Hunter
  13. J. of Coll. and Inter Sc. v.164 no.1 Caloimetry of Poly-(Acrylic Acid) Adsorption on TiO₂ M.R. Bohmer;Y.E. Sofi;A. Foissy