전로슬래그를 이용한 Modified Belite Cement의 제조에 관한 연구

A Study on the Preparation of Modified Belite Cement Using Converter Slag

  • 박종옥 (국립공업기술원 요업기술원) ;
  • 김승진 (한국 건자재 시험연구원) ;
  • 박홍수 (명지대학교 공과대학 화학공학과) ;
  • 신현택 (경상대학교 공과대학 무기재료공학과)
  • 발행 : 1995.08.01

초록

In order to prepare the modified belite (C2S-C4A3S-C4AF-CS) cement with low energy, clinkers were synthesized by converter slag, limestone, gypsum and clay. The synthesized clinkers were characterized and the hydration processes were investigated by XRD, SEM and microconduction calorimetry. The hydrates were mainly C-S-H and ettringite. The needle-like ettringite formed by the hydration of C4A3S at the early stage of hydration was filled in the inner vacant spaces of the hardened body and it might contribute to the rapid-hardening phenomena. The hardened body became stronger due to the hydration of C2S at the later period. The compressive strengths of the cement-3 mortars hydrated for 3, 7 and 28 days were 115, 128 and 211 Kgf/$\textrm{cm}^2$, respectively.

키워드

참고문헌

  1. 9th Inter. Cong. Chem. Cement v.1 Effect of Energy Conservation and Environmental Control Measures on Clinker Properties S. Sprung;M. Delort
  2. World Cement Technology v.11 no.4 Investigations of Energy Saving Cement P.K. Mehta
  3. Zement Kalk Gips v.41 no.4 International Development Trends in Low Energy Cement J. Stark;A. Mullerd
  4. Cement Chemistry(2nd ed.) H.F.W. Tayler
  5. 6th Inter. Cong. Chem. Cement v.Ⅲ-4 Alumina-Belite Cement L.A. Zaharow
  6. 7th Inter. Cong. Chem. Cement v.3 High Strength Cement in the CaO-Al₂O₃-SiO₂-SO₃System and Its Application G. Sudoh(et al.)
  7. 8th Inter. Cong. Chem. Cement v.2 Research on the Early Strength Cement Containg High Content of Iron F. Xiuji;Z. Yufeng
  8. J. Kor. Cerm. Soc. v.27 no.2 Synthesis and Hydration of Modified Belite Cement Clinker C.B. Kim;K.S. Han;S.H. Choi
  9. 3rd Bejing Inter. Symp. Cem. Concrete v.1 Development of Modified Belite Cement W.H. Chae;S.H. Choi;K.S. Han
  10. Am. Assoc. Petrol. Bull. v.43 R.L. Butt
  11. セメント技術年報(日) v.34 no.98 早强高爐セメントの製造 秋山桂一;太田械
  12. Cem. Conc. Res. v.11 C₄A₃S Hydration Ettringite Formation and its Expansion Mechanism;1. Expansion; Ettringite Stability K. Ogawa;D.M. Roy
  13. 8th Inter. Cong. Chem. Cement v.2 An Investigation into cement CaO-SiO₂-Al₂O₃-Fe₂O₃-SO₃System Wang Yaumou
  14. Cement Technology Studies of Ettringite and its Derivatives J. Bensted
  15. Cement & Concrete v.548 The Characteristics of Ultra High-Early Strength Concrete Put Using Ettingite Additive H. Kawano(et al.)
  16. Cem. Conc. Res. v.23 no.2 Rapid Setting Magnesium Phosphate Cement for Quick Repair of Concrete Pavements Characterisation and Durability Aspects S.S. Seehra;Saroj. Guota&Stander