클로로메틸폴리스티렌의 고분자 반응에 관한 연구(VI) 용매가 클로로메틸폴리스티렌의 자동가교에 미치는 영향

Polymeric Reaction of Chloromethylpolystyrene(VI) Effect of Solvent on the Autocrosslinking of Chloromethylpolystyrene-

  • 발행 : 1995.09.01

초록

The amount and the degree of autocrosslinking in induced autocrosslinking of crosslinked chloromethylpolysty- rene(I'CMS) were measured quantitatively. In the chloromethylation reaction of the crosslinked polystyrene(PS), two factors, the type of crosslinking agent and the deyu of crosslinking determine the autocrosslinking mechanism. In the induced autocrosslinking reaction of PCMS, however, the dielectric constant(e) of the solvent used for the reaction determines the autocrosslinking. It has been shown that amount of autocrosslinking increased in the order of tetrachloroethane

키워드

참고문헌

  1. 한국섬유공학회지 v.24 전동원;이혜자
  2. 한국섬유공학회지 v.24 전동원;이혜자
  3. 이화여자대학교 생활과학연구원 논총 v.42 전동원
  4. 한국섬유공학회지 v.28 전동원;정은주
  5. 한국섬유공학회지 v.28 전동원;홍주석;이혜자
  6. Die Angewandte Makromolekulare Chemie v.80 M.Negre;M.Bartholin;A.Buyot
  7. 한국섬유공학회지 v.24 전동원;이원철;손진언;홍성일