Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Molybdenum(VI), -(V), and -(IV) Oxo Complexes with S-methyl 3-(2-hydroxypheny)methylenedithiocarbazate and Its Derivatives

  • Hee-Jung Kim (Department of Chemistry Education, Hyosung Women's University) ;
  • Bon-Kweon Koo (Department of Chemistry Education, Hyosung Women's University)
  • Published : 1994.09.20
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Abstract

A number of molybdenum(VI), -(V), and -(IV) oxo complexes with S-methyl 3-(2-hydroxyphenyl)methylenedithiocarbazate and its derivatives as the ONS-donor metal-binding substrate are synthesized. The Mo(VI)-dioxo complexes are cis-dioxo Mo$O_2$L(D), where D is solvent molecules such as MeOH, DMF, Py(pyridine), DMSO, and ${\gamma}$-Pic(${\gamma}$-picoline). The Mo(V)-oxo complexes are of the type (PyH)[MoO(NCS$)_2$L] with an octahedral geometry. The Mo(IV)-oxo complexes, MoOL are derived from corresponding Mo(VI)-dioxo complexes by oxo abstraction with PP$h_3$. The complexes are characterized by IR, $^1$H-NMR, UV-Vis spectroscopy and cyclic voltammetry. On the basis of ligand displacement reaction, the qualitative order of D binding for Mo$O_2$L(D) complexes is also discussed.

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References

  1. J. Am. Chem. Soc. v.107 Berg, J. M.;Holm, R. H.
  2. Inorg. Chem. v.23 Topich, J.;Lyon, J. T.
  3. Inorg. Chem. v.27 Gheller, S. F.;Newton, W. E.;Majid, L. P.;Bradbury, J. R.;Schultz, F. A.
  4. J. Am. Chem. Soc. v.109 Young, C. G.;Robert, S. A.;Ortega, R. B.;Enemark, J. H.
  5. Inorg. Chem. v.17 Schultz, F. A.;Ott, V. R.;Rolinson, D. S.;Bravard, D. C.;McDonald, J. W.;Newton, W. E.
  6. J. Chem. Soc.,Dalton Trans. Ghosh, P.;Bandyopadhyay, P.;Chakravorty, A.
  7. Inorg. Chem. v.28 Purohit, S.;Koley, A. P.;Prasad, L. S.;Manoharan, P. T.;Ghosh, S.
  8. Molybdenum Chemistry of Biological Significance Bray, R. C.
  9. Prog. Inorg. Chem. v.22 Stiefel, E. I.
  10. J. Am. Chem. Soc. v.101 Berg, J. M.;Hodgson, K. O.;Cramer, S. P.;Corbin, J. L.;Elsberry, A.;Pariyadath, N.;Stiefel, E. I.
  11. J. Am. Chem. Soc. v.103 Cramer, S. P.;Wahl, R.;Rajagopalan, K. V.
  12. J. Chem. Soc. Dalton Trans. Bhattacharjee, S.;Bhattacharyya, R.
  13. Inorg. Chim. Acta v.7 Sabat, H.;Rudolf, M. F.;Tezowska-Trzebltowska, B.
  14. Vogel's Textbook of Practical Organic Chemistry Furniss, B. S.;Hannaford, A. J.;Smith, P. W. G.;Tatchell, A. R.
  15. Inorg. Chim. Acta v.7 Ali, M. A.;Livingstone, S. E.;Philips, D. J.
  16. Inorg. Chim. Acta. v.19 Das, M.;Livingstone, S. E.
  17. Coord. Chem. Rev. v.7 Geary, W. J.
  18. Bull. Korean Chem. Soc. v.13 Kim, J. S.;Koo, B. K.
  19. J. Chem. Soc. Dalton. Trans March, A.;Duatti, A.;Rossi, R.;Magon, L.;Pasqualin, R.;Bertolasi, V.;Ferretti, V.;Gilli, G.
  20. Inorg. Chem. v.20 Rajan, O. A.;Chakravorty, A.
  21. Inorg. Chem. v.22 Berg, J. M.;Holm, R. H.
  22. J. Chem. Soc., Dalton. Trans. Bailey, N. A.;Fenton, D. E.;Winter, D. J.
  23. Inorg. Chem. v.29 Pillai, M. R. A.;John, C. S.;Lo, J. M.;Schlemper, E. O.;Troutner, D. E.
  24. Tables of Spectral Data for Structure Determination of Organic Compound Pretsch, E.;Seibl, J.;Simon, W.;Clere, T.;Biemann, K.
  25. J. Chem. Soc., Dalton. Trans. Chaudhury, M.
  26. Prog. Inorg. Chem. v.22 Lippard, S. J.
  27. Inorg. Chem. v.21 Boyd, I. W.;Spence, J. T.
  28. J. Am. Chem. Soc. v.107 Kaul, B. B.;Enemark, J. H.;Merbs, S. L.;Spence, J. T.
  29. Inorg. Chem. v.23 Subamian, P.;Spence, J. T.;Ortega, R.;Enemark, J. E.
  30. Inorg. Chem. v.17 Taylor, R. D.;Street, J. P.;Minelli, M.;Spence, J. T.
  31. Inorg. Chem. v.20 Topich, J.
  32. J. Chem. Soc., Dalton. Trans. Bhattacharjee, S.;Bhattacharyya, R.
  33. Coord. Chem. Rev. v.1 Mitchel, P. C. H.
  34. Inorg. Chem. v.24 Chaudhury, M.
  35. Infrared Spectra of Inorganic and Coordination Compound Nakamoto, K.
  36. Transition Met. Chem. v.10 Symal, A.;Bari Niazi, M A.

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