Bulletin of the Korean Chemical Society

  • 제15권6호
  • /
  • Pages.456-460
  • /
  • 1994
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Studies on Electrochemical properties of Lithium/Oxyhalide Cell: Electrocatalytic Effects on the Reduction of Thionyl Chloride

  • Kim Woo Seong (Department of Chemistry, Chonnam National University) ;
  • Choi Yong-Kook (Department of Chemistry, Chonnam National University) ;
  • Chjo Ki-Hyung (Department of Chemistry, Chonnam National University)
  • 발행 : 1994.06.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Catalytic effects of various cobalt phenylporphyrin compounds on the reduction of thionyl chloride at glassy carbon electrode have been evaluated by determining kinetic parameters with cyclic voltammetric techniques. The concentration of catalysts and the electrode immersion time have been found to affect the catalyst performance strongly, leading to a conclusion that the compounds are first adsorbed at the electrode surface and act as catalysts. Significant improvements in cell performance have been noted in terms of both exchange rate constants of up to 3 times and current densities of up to 150% at glassy carbon electrode.

키워드

참고문헌

  1. J. Electrochem. Soc. v.126 Schlaikjer, C. R.;Goelbel. F.;Marincic, N.
  2. J. Electrochem. Soc. v.126 Bowden, W.;Dey, A. N.
  3. Lithium Battery Technology Salmon, D. J.;Adamczyk, M. E.;Hendricks, L. L.;Abels, L. L.;Hall, J. C.;Venkatasetty, H. V.(ed.)
  4. Soviet Electrochem. v.17 Kolomoets, A. M.;Pleshakov, M. S.;Dudnikov, V. I.
  5. Proc. 30th Power Sources Symp. Doddapaneni, N.
  6. J. Electrochem. Soc. v.129 Istone, W. K.;Brodd, R. J.
  7. J. Electrochem. Soc. v.131 Istone, W. K.;Brodd, R. J.
  8. J. Electrochem. Soc. v.131 Madou, M. J.;Szpak, S.
  9. J. Power Sources v.24 Hagan, W. P.;Hampson, N. A.;Packer, R. K.
  10. Lithium Batteries, Proceeding. 87-1 Delnick, F. M.;Cieslak, W. R.;Peebles, D. E.;Rodgers, Jr. J. W.;Dey, A. N.(ed.)
  11. J. Electrochem. Soc. v.134 Madou, M. J.;Smith, J. J.;Szpak, S.
  12. J. Power Sources v.21 Chiu, J. G.;Wang, Y. Y.;Wany, C. C.
  13. J. Electrochem. Soc. v.140 Choi, Y. K.;Kim, B. S.;Park, S. M.
  14. J. Power Sources v.24 Hills, A. J.;Hampson, N. A.
  15. J. Electrochem. Soc. v.136 Mosier-Boss, P. A.;Szpak, S.;Smith, J. J.;Nowak, R. J.
  16. J. Power Sources v.26 Bagotsky, V. S.;Kazarinov, V. E.;Vol'fkovich, Yu. M.;Kanevsky, L. S.;Beketayeva, L. A.
  17. J. Power Sources v.26 Hu, H. Y.;Ko, S. W.
  18. J. Power Sources v.26 Schlaikjer, K. R.
  19. Proc. 30th power Symp. Doddapaneni, N.
  20. Proc. 31th power Symp. Doddapaneni, N.
  21. Proc. Symp. Lithium Batteries v.84-1 Doddapaneni, N.
  22. Proc. Electrochem. Soc. v.84-12 Doddapaneni, N.
  23. Proc. Electrochem. Soc. v.87-12 Zagal, J. H.;Paez, C.;Barbato, S.
  24. Proc. 32nd power Symp. Doddapaneni, N.
  25. J. Am. Chem. Soc. v.114 Karaman, R.;Blasco, A.;Arasasingham, O.;Bruice, T. C.
  26. Inorg. Chem. v.29 Bernstein, P. A.;Lever, A. B. P.
  27. Electrochemical Methods Bard, A. J.;Faulkner, L. R.
  28. Electrochemical Methods Bard, A. J.;Faulkner, L. R.

피인용 문헌

  1. Electrocatalytic effects of thionyl chloride reduction by polymeric Schiff base transition metal(II) complexes vol.252, pp.1, 2003, https://doi.org/10.1016/s0926-860x(03)00414-9
  2. Synthesis, Structure and Characterization of Schiff Base Metal Complexes and Their Electrochemical Properties of Thionyl Chloride Reduction vol.26, pp.6, 1994, https://doi.org/10.1002/cjoc.200890191
  3. The synthesis of Cu(II), Zn(II), and Co(II) metalloporphyrins and their improvement to the property of Li/SOCl2 battery vol.18, pp.12, 1994, https://doi.org/10.1007/s10008-014-2571-3
  4. Multi-Walled Carbon Nanotubes Chemically Modified by Cobalt Tetraaminophthalocyanines with Excellent Electrocatalytic Activity to Li/SOCl2 Battery vol.161, pp.14, 1994, https://doi.org/10.1149/2.0951414jes
  5. The synthesis of porphyrin and metalporphyrins and their improvement to the property of Li/SOCl2 primary battery vol.52, pp.1, 1994, https://doi.org/10.1134/s1023193516010055
  6. Carbon Nanotubes Chemically Modified by Metal Phthalocyanines with Excellent Electrocatalytic Activity to Li/SOCl2 Battery vol.164, pp.6, 1994, https://doi.org/10.1149/2.0611706jes