Bulletin of the Korean Chemical Society

  • 제15권6호
  • /
  • Pages.436-442
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  • 1994
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Comparison of the Ligating Ability of Anonic Transition Metal Complex $(Mn(CO)_{5}{^-})$, Transition Metal Hydrides $(HCr(CO)_{5}{^-},\;HW(CO)_{5}{^-},\;cis-HW(CO)_{4}P(OMe)_{3}{^-},\;HFe(CO)_{4}{^-},\;trans-\;HFe(CO)_{3}P(OMe)_{3}{^-})$, and Traditional Ligands $(Br^-,\;P(C_{6}H_{5})_{3})\;to\;M(CO)_{5}{^0}$ (M = Cr, W)

  • Park, Yong K (Department of Chemistry, Kangwon National University) ;
  • Han, In S (Department of Chemistry, Kangwon National University) ;
  • Marcetta Y. Darensbourg (Department of Chemistry, Texas A&M University, College Station)
  • 발행 : 1994.06.20
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초록

Heterobimetallic complexes have a donor-accepter metal-metal bond in which two electrons from the electron-rich metal moiety are donated to the other electron-deficient one. Based on the competition reactions, Cotton-Kraihanzel force constants, ν(CO)IR band resolution and the relative nucleophilicity comparison of the donor ligands, the following relative ligating ability of the donor ligands toward $M(CO)_5$ (M=Cr, W) is assessed: cis-HW$(CO)_4P(OMe)_3^-$, $HW(CO)_5^-$ > $HCr(CO)_5^-$-$Br^-$ > trans-HFe$(CO)_3P(OMe)_3^-$ > $Mn(CO)_5^-$ > $HFe(CO)_4^-$ > PP$h_3$

키워드

참고문헌

  1. Comprehensive Organometallic chemistry Roberts, D. A.;Gedffroy, G. L.;G. Wilkinson(ed.)
  2. Organometallics v.3 Casey, C. P.;Bullock, R. M.
  3. J. Am. Chem. Soc. v.108 Arndt, L. W.;Darensbourg, M. Y.;Delord, T.;Bancroft, B. T.
  4. Organometallics v.5 Rosenberg, S.;Mahoney, W. S.;Hayes, J. M.;Geoffroy, G. L.
  5. Acc. Chem. Res. v.20 Bullock, R. M.;Casey, C. P.
  6. Organometallics v.8 Davis, H. B.;Einstein, F. W. B.;Glavina, P. G.;Jones, T.;Pomeroy, R. K.;Rushman, P.
  7. Organometallics v.9 Antonelli, D. M.;Cowie, M.
  8. J. Am. Chem. Soc. v.110 Davis, H. B.;Einstein, F. W. B.;Johnston, V. J.;Pomeroy, R. K.
  9. Inorg. Chem. v.26 Einstein, F. W. B.;Jennings, M. C.;Krentz, R.;Pomeroy, R. K.;Rushman, P.;Willis, A. C.
  10. J. Chem. Soc., Chem. Commun. Einstein, F. W. B.;Pomeroy, R. K.;Rushman, P.;Willis, A. C.
  11. Organometallics v.4 Einstein, F. W. B.;Pomeroy, R. K.;Rushman, P.;Willis, A. C.
  12. J. Organomet. Chem. v.408 Park, Y. K.;Kim, S. J.;Kim, J. H.;Han, I. S.;Lee, C. H.;Choi, H. S.
  13. J. Am. Chem. Soc. v.89 Anders, U.;Graham, W. A. G.
  14. J. Am. Chem. Soc. v.97 Levenson, R. A.;Gray, H. B.
  15. J. Am. Chem. Soc. v.107 Tooley, P. A.;Arndt, L. W.;Darensbourg, M. Y.
  16. J. Am. Chem. Soc. v.107 Gaus, P. L.;Kao, S. C.;Youngdahl, K.;Darensbourg, M. Y.
  17. J. Am. Chem. Soc. v.88 Hayter, R. G.
  18. Organometallics v.6 Lee, K. Y.;Kuchynka, D. J.;Kochi, J. K.
  19. J. Am. Chem. Soc. v.104 Darensbourg, M. Y.;Jimmemez, P.;Sackett, J. R.;Hemkel, J. M.;Kump. R. L.
  20. Inorg. Synth. v.22 Slater, S. G.;Darensbourg, M. Y.
  21. Organometallics v.1 Slater, S. G.;Lusk, R.;Schumann, B. P.;Darensbourg, M. Y.
  22. Inorg. Chem. v.17 Darensbourg, M. Y.;Darensbourg, D. J.;Barros, H. L. C.
  23. Ph. D. Dissertation, University of Texas Edens, M. W.
  24. J. Am. Chem. Soc. v.104 Chem, Y. S.;Ellis, J. E.
  25. J. Am. Chem. Soc. v.84 Cotton, F. A.;Kraihanzel, C. S.
  26. J. Am. Chem. Soc. v.100 Kinney, R. J.;Jones, W. D.;Bergman, R. G.
  27. J. Am. Chem. Soc. v.106 Arndt, L. W.;Delord, T.;Darensbourg, M. Y.
  28. J. Am. Chem. Soc. v.99 Meneil, E. A.;Scholer, F. R.
  29. Prog. Inorg. Chem. v.32 Hall, K. P.;Mingos, D. M. P.
  30. Inorg. Chem. v.14 Johnson, J. R.;Duggan, D. M.;Risen, W. M.
  31. Inorg. Chem. v.12 Johnson, J. R.;Ziegler, R. J.;Risen, W. M.
  32. J. Chem. Soc., Dalton Trans. Onaka, S.;Sugawara, T.;Kawada, Y.;Iwamura, H.
  33. Organometallics v.5 Ash, C. E.;Delord, T.;Simmons, D.;Darensbourg, M. Y.
  34. Inorg. Chem. v.7 Ruff, J. K.
  35. Organometallics v.3 Kao, S. C.;Darensbourg, M. Y.;Schenk, W.
  36. Organometallics v.3 Kao, S. C.;Darensbourg, M. Y.
  37. J. Am. Chem. Soc. v.108 Halpin, C. F.;Hall, M. B.
  38. Inorg. Chem. v.18 Darensbourg, M. Y.;Barrows, H. L. C.
  39. Organometallics v.4 Warner, K. E.;Norton, J. R.

피인용 문헌

  1. Kinetic Studies on the Reaction of the Homobimetallic Anion, M+(η5-MeCp)Mn(CO)2Mn(CO)5-(M+=Na+, PPN+) with A vol.48, pp.5, 1994, https://doi.org/10.5012/jkcs.2004.48.5.473