Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

The Effect of Iron Catalysts on the Formation of Alcohol and Ketone in the Biomimetic Oxidation of Cyclohexane

  • Kim Seong-Bo (Korea Research Institute of Chemical Technology) ;
  • Lee Kyu-Wan (Korea Research Institute of Chemical Technology) ;
  • Kim, Yong-Joon (Department of Chemical Engineering, Korea University) ;
  • Hong Seog-In (Department of Chemical Engineering, Korea University)
  • Published : 1994.06.20
Download PDF
⟨ Previous Next ⟩

Abstract

Effects of iron compounds in known biomimetic oxidation systems (Gif IV and GoAgg II) have been studied on activity and ketone/alcohol selectivity of cyclohexane oxidation. Both ketone/alcohol ratio and cyclohexane conversion were affected by counter-ion Z of iron compounds Z-Fe. When Z has a more electron withdrawing property, the reactivity is increased and the formation of ketone is favored. From these experimental results, a new mechanism is proposed for the biomimetic oxidation system.

Keywords

References

  1. Biochim, Biophys. Acta. Woodland, M. P.;Patil, D. S.;Cammack, R.
  2. FASEB v.3 Kivirkko, K. I.;Myllyla, R.;Pihalajaniemi, T.
  3. J. Heterocycle. Chem. v.27 Baldwin, J. E.
  4. J. Am. Chem. Soc. v.112 Ziering, D. L.;Pascal, Jr. R. A.
  5. Tetrahedron v.47 Suga, A.;Sugiyama, T.;Otsuka, M.;Sugiura, M. Y.;Maeda, K.
  6. J. Chem. Soc., Chem. Commun. v.41 Barton, D. H. R.;Gastiger, M. J.;Motherwell, W. B.
  7. Tetrahedron v.46 Barton, D. H. R.;Lee, K. W.;Mehl, W.;Ozbalik, N.;Zhang, L.
  8. Bull. Kor. Chem. Soc. v.12 no.5 Lee, K. W.;Kim, S. B.;Barton, D. H. R.;Doller, D.
  9. J. Am. Chem. Soc. v.107 Collman, J. P.;Brauman, J. I.;Meunier, B.;Hayashi, T.;Kodadek, T.;Ray Buck, S. A.
  10. Mol. Pharmacol v.18 Oritz, P. R.;Mico, B. B. A.
  11. J. Am. Chem. Soc. v.111 Garrison, J. M.;Bruice, T. C.
  12. J. Am. Chem. Soc. v.114 Barton, D. H. R.;Beviere, S. D.;Chavasiri, W.;Csuhai, E.;Doller, D.

Cited by

  1. A reaction kinetic study on the Gif-type biomimetic oxidation of cyclohexane vol.12, pp.2, 1994, https://doi.org/10.1007/bf02705645
  2. The reaction of [Fe(pic)3] with hydrogen peroxide: a UV-visible and EPR spectroscopic study (Hpic = picolinic acid) vol.2005, pp.16, 1994, https://doi.org/10.1039/b504897d