Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Catalytic and Stoichiometric Hydroacylation of Olefin Derivatives with 8-Quinolinecarboxaldehyde by Rh(I)

  • Published : 1994.03.20
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Abstract

Catalytic hydroacylation has been achieved by the reaction of 8-quinolinecarboxaldehyde (1) and various vinyl derivatives such as 2a, 2b and 2c with Wilkinson's complex (3) to give linear alkyl ketones, 4a, 4b and 4c, respectively. However, stoichiometric ligand-promoted hydroacylation of 2a and 2b with [$(C_8H_{14})_2RhCl]_2$ (5) resulted in a mixture of the branched alkyl ketones and the linear alkyl ketones in different ratios. Stoichiometric hydroacylation of some other olefin derivatives such as 6, 11, 12 and 26, produced functionalized alkyl ketone compounds.

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References

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  1. ChemInform Abstract: Catalytic and Stoichiometric Hydroacylation of Olefin Derivatives with 8-Quinolinecarboxaldehyde by Rh(I). vol.25, pp.40, 1994, https://doi.org/10.1002/chin.199440157
  2. Traceless Chelation‐Controlled Rhodium‐Catalyzed Intermolecular Alkene and Alkyne Hydroacylation vol.19, pp.9, 1994, https://doi.org/10.1002/chem.201204056