Bulletin of the Korean Chemical Society

  • 제15권2호
  • /
  • Pages.145-150
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  • 1994
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Spectroscopic Properties and Ligand Field Analysis of Tris[($\pm$)-trans-1,2-cyclohexanediamine]chromium(Ⅲ) Chloride$^1$

  • Jong-Ha Choi (Department of Chemistry, Andon National University)
  • 발행 : 1994.02.20
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초록

The low temperature luminescence and excitation, room-temperature UV-visible and infrared spectra of [Cr(${\pm})chxn_3]Cl_3$ (chxn=trans-1,2-cyclohexanediamine) have been measured. It is found that the zero-phonon line in the excitation spectrum splits into two components by $47\;cm^{-1}$. The eight electronic transitions due to spin-allowed and spin-forbidden are assigned. As expected, nitrogen atoms of chxn ligand have strong ${\sigma}-donor $properties toward chromium(Ⅲ). The positions and splittings of sharp-line transitions are analyzed as a function of the Cartesian bite (${\alpha}$) and twist (${\beta}$) angles to predict the metal-ligand geometry.

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참고문헌

  1. Bull. Basic Sci. Andong Univ. v.4 Choi, J-H.;Oh, I-G.
  2. Coord. Chem. Rev. v.70 Hoggard, P. E.
  3. Curr. Top. Chem. Hoggard, P. E.
  4. Inorg. Chem. v.17 Wilson, R. B.;Solomon, E. I.
  5. J. Chem. Soc. Faraday Trans. II v.72 Flint, C. D.;Matthews, A. P.
  6. Bull. Korean Chem. Soc. v.14 Choi, J-H.
  7. Bull. Korean Chem. Soc. v.14 Choi. J-H.;Oh, I-G.
  8. Inorg. Chim. Acta v.L27 Wasgestian, F.;Gowin, E.
  9. Acta Chem. Scand. v.32A Harnung, S. E.;Laier, T.
  10. Acta Cryst. v.B48 Morooka, M.;Ohba, S.;Miyamae, H.
  11. Bull. Chem. Soc. Jpn. v.63 Iida, M.;Iwaki, M.;Matsuno, Y.;Yokoyama. H.
  12. Bull. Chem. Soc. Jpn. v.64 Iida, M.;Yokoyama, H.
  13. Inorg. Chem. v.24 Kaizaki, S.;Ito, M.;Nishimura, N.;Matsushita, Y.
  14. Acta Chem. Scand. v.24 Pederson, E.
  15. Inorganic Electronic Spectroscopy(2nd ed.) Lever, A. B. P.
  16. J. Inorg. Nucl. Chem. v.39 Sonar, M. H.;Murty, A. S. R.
  17. Polyhedron v.11 Choi, J-H.;Hoggard, P. E.
  18. Spectrochim. Acta v.22 Nakagawa, I.;Shimanouchi, T.
  19. Inorg. Chem. v.20 Geiser, U.;Gudel, H. U.
  20. Phys. Rev. v.83 Trees, R. E.
  21. Inorg. Chem. v.30 Hoggard, P. E.
  22. Computer J. v.7 Powell, M. J. D.
  23. Optimization Techniques with Fortran Kuester, J. L.;Mize, J. H.
  24. Multivariate Error Analysis Clifford, A. A.
  25. Ber. Bunsenges. Phys. Chem. v.90 Urushiyama, A.;Schonherr, T.;Schmidtke, H-H.
  26. Inorg. Chem. v.27 Lee, K-W.;Hoggard, P. E.
  27. Transition Met. Chem. v.16 Lee, K-W.;Hoggard, P. E.
  28. Inorg. Chem. v.27 Hoggard, P. E.
  29. Coord. Chem. Rev. v.43 Lever, A. B. P.

피인용 문헌

  1. Electronic and Vibrational Spectroscopy of cis-Diisothiocyanato(1,4,8,11-tetraazacyclotetradecane)chromium(Ⅲ) Thiocyanate vol.24, pp.3, 1994, https://doi.org/10.5012/bkcs.2003.24.3.384
  2. Spectroscopic Properties and Ligand Field Analysis of trans -Dibromo(2,2-dimethyl-1,3-diaminopropane)chromium(III) Moiety vol.26, pp.6, 1994, https://doi.org/10.5012/bkcs.2005.26.6.903
  3. Crystal Structure and Spectroscopic Properties of cisβ-[CrCl_2(1,4,8,11-tetrazaundecane)chromium(III) Perchlorate vol.29, pp.7, 1994, https://doi.org/10.5012/bkcs.2008.29.7.1399
  4. Synthesis, Spectroscopic and Ligand Field Properties of trans-Difluorobis(2,2-dimethylpropane-1,3-diamine)chromium(III) Perchlorate vol.32, pp.1, 1994, https://doi.org/10.5012/bkcs.2011.32.1.296
  5. Spectroscopic Properties and Ligand Field Analysis of trans-[Cr(Me2tn)2(OH)(H2O)](ClO4)2 vol.58, pp.6, 2014, https://doi.org/10.5012/jkcs.2014.58.6.681
  6. Spectroscopic Properties and Magnetic Behavior of [Cr(urea)6][Cr2O7]Br·H2O vol.61, pp.2, 1994, https://doi.org/10.5012/jkcs.2017.61.2.77