$TiO_2$ Doped Sapphire Single Crystal Growth by Verneuil Method and Study for Defects

Verneuil법에 의한 $TiO_2$를 첨가한 Sapphire 단결정 성장과 결함에 관한 연구

  • Cho, H. (Dept. of Inorganic Materials Eng., Hanyang University) ;
  • Choi, J.K. (Dept. of Inorganic Materials Eng., Hanyang University) ;
  • Chun, B.S. (Dept. of Inorganic Materials Eng., Hanyang University) ;
  • Orr, K.H. (Dept. of Inorganic Materials Eng., Hanyang University) ;
  • Park, H.S. (Hongik University, College of Science and Technology, Dept. of Inorganic Materials Eng)
  • 조현 (한양대학교 공과대학 무기재료공학과) ;
  • 최종건 (한양대학교 공과대학 무기재료공학과) ;
  • 전병식 (한양대학교 공과대학 무기재료공학과) ;
  • 오근호 (한양대학교 공과대학 무기재료공학과) ;
  • 박한수 (홍익대학교 과학기술대학 무기재료공학과)
  • Published : 1994.12.01

Abstract

TiO2 doped sapphire single crystals were grown by Verneuil method. The doping amount of TiO2 to Al2O3 were varied 0.1, 0.2, 0.3 wt% respectively. The grown crystals have reddish color and somewhat transparent. Optimum growth condition was established by changing growth rate and gas flow ratio. Growth condition are as follows; The flow rate range of oxygen ws 5.0~7.3 ι/min and that of hydrogen was 16~25ι/min and average growth rate was 6~8mm/hr. The basic cause of color appearence and defects in crystal were studied.

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References

  1. Oxide Ceramics Eugene Ryshkewitch;David W. Richerson
  2. Crystals v.2 no.24 Kurt Nassau;Julia Nassau
  3. Advanced Crystal Growth Peter M. Dryburgh;Brian Cockaye;Keith G. Barraclough
  4. Ann Chim. Phys. v.3 no.20 A. Verneuil
  5. Compt Rend v.135 no.79 A. Verneuil
  6. The Physics and Chemistry of Color Kurt Nassau
  7. Crystal Growth v.2 C.H.L. Goodman
  8. Etching of Crystals Keshra Sangwal
  9. Br Ceram. Soc. v.6 no.1 L.M. Davis
  10. Phil. Mag. A v.42 Precipitation in Star Sapphire, Ⅰ. Identification of the Precipitate Phillips, D.S.;Heuer, A.H.;Mitchell, T.E.