인산화 가교 키토산의 합성 및 금속이온 흡착 특성(II)-인산화 가교 키토산의 금속이온 흡착 특성-

Synthesis of Crosslinked Chitosan Phosphate and Its Metal Ion Adsorption Characteristics(II)-Metal ion Adsorption Characteristics of Crosslinked Chitosan Phosphate-

  • 이종순 (서울대학교 섬유고분자공학과) ;
  • 홍성일 (서울대학교 섬유고분자공학과, 이화여자대학교 의류직물과) ;
  • 전동원
  • 발행 : 1994.12.01

초록

With the epichlorohydrin antral PIOi-methanesulfonic acid system, crosslinked chitosan phosphate(p-c-chitosan). a new biodegradable chelating polymer, was synthesized successfully as reported in the previous paper Metal ion adsorption characteristics and selectivity tests for p-c-chitosan were carried out in 100/200ppm of various metal ion standard solutions(Cu2+. Co2+, Ci2+, Cd2+, Nn2+) by batch method. The adsorption capacity vat measured by an Atomic Absontion Spectroscopy(AAS) with appropriate adsorption time interval. According to the results, it was elucidated that the adsorption capacity of p-c-chitosan was influenced by crosslinking ratio and phosphate content and p-c-chitosan showed high adsorption equilibrium rate as well as high adsorption cilpacity. And p-c-chitosan showed more selective adsorption of Co2+ than Cu2+ in 200ppm mixed solution or Cu2+/Co2+.

키워드

참고문헌

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