The Rheological Properties and Die-swell of Bicomponent Blends of Polyethylene, Polypropylene, and Polystyene

폴리에틸렌, 폴리프로필렌, 폴리스티렌 이성분 혼합물의 유변학적 성질 및 다이 팽윤

  • 김형섭 (서울대학교 섬유고분자공학과) ;
  • 김상용 (서울대학교 섬유고분자공학과, 성균관대학교 섬유공학과) ;
  • 전붕수
  • Published : 1994.10.01

Abstract

A study has been made on the die-swell and rheological properties of bicemponent polymer blends of low density polyethylene(PE), polypropylene(PP) and polystyrene(PS); PE/PP, PE/PS, and PP/PS. In the case of PE/PP blends the continuous phase transferred from PE to PP at the PE content of 60wt%. Meanwhile the PE/PS and PP/PS blends the continuous phase transferred from PE to PS and from PP to PS at the PS content of 60wt%. respectively. The die-swelling ratio. normal stress difference(N1) and dynamic shear viscosity of PE/PP blends appear, to show same tendency by chaneine the blend-ratios. For the cases of both PE/PS and PP/PS blends, where PE and PP are in the continuous phase, the die-swelling ratios increase as the N1 increases but decrease as the dynamic shear viscosity increases. But N1 of the PS has been found not to contribute to the die-swelling ratios when PS is in the continuous phase.

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