Studies on the On-line Dry-Jet Wet Spinning of Polyacrylonitrile(I)- Design Factors of Polymerization to Match Desired Spinnability-

아크릴고분자의 온-라인 건습식방사공정에 관한 연구(I)-방사성 조절을 위한 중합요인-

  • 민병길 (한국과학기술연구원 고분자연구부) ;
  • 김병철 (한국과학기술연구원 고분자연구부, 한국과학기술연구원 고분자연구부, 한국과학기술연구원 고분자연구부, 성균관대학교 섬유공학과, 성균관대학교 섬유공학과, 성균관대학교 섬유공학과, 제일합섬 기술연구소)
  • Published : 1994.08.01

Abstract

The polymerization factors to meet the desired physical properties of polyacrylonitrile(PAN) spinning dope for on-line spinning were examined. The spinning dope was prepared by solution polymerization in dimethylsulfoxide solution induced by azobis-iso-butyronitrile. The physical properties of the spinning dope could be controlled by manipulating monomer concentration, initiator concentration and polymerization temperature. At the unusually high monomer concentrations, required in the on-line spinning process, the polymerization of PAN exhibited a little deviation from the theoretical prediction.

Keywords

References

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