Synthesis and Properties of Aromatic Poly(ether-alnide-imide)s

방향족 폴리(에테르-아미드-이미드)중합체와 합성과 그 특성

  • 안영무 (한성대학교 의류직물학과) ;
  • 손태원 (한국과학기술연구원 섬유고분자실, 서울대학교 섬유고분사공학과) ;
  • 홍성일
  • Published : 1994.07.01

Abstract

Three different poly(ether-amide imide)s[PEAI], containing benzophenone, bisphenol A and suifone units, have been syllthesized from corresponding poly(ether-amide-allelic aci(B) s[PEAAA] by means of cyclodehydration which were obtained from the reaction of trimellitic anhydride chloride(TMAC) with 4,4'-bis (m-aminophenoxy) benzophenone, 2,2-bis(4-(m-aminophenoxy) phenyl)propane and 4,4'-bis(m-aminophenoxy) diphenyl sulfone, respectively. It hat bell revealed that all PEAI's are thermally stable (temperatures at 5% weight loss are 480-504℃) and have the glass transition temperatures(in the vicinity of 200℃) suitable to be processed by conventional extrusion or injection molding. And also they show the good solubility to polar organic solvents, such as pyridine, N,N-dimethyl formamide and dimethylsulfoxide.

Keywords

References

  1. J. Appl. Polym. Sci. v.26 B.A.reinhardt;F.E.Arnold
  2. J. Kor. Soc. Tex. Eng. Chem. v.25 Y.M.Ahn;S.I.Hong;C.J.lee;T.W.Son
  3. Polymer v.13 Y.M.Ahn;T.W.Son;S.I.Hong
  4. J. Kor. Fib. Soc. v.27 Y.M.Ahn;T.W.Son;S.I.Hong
  5. Am. Chem. Soc. Polymers for High Technology A.K.St.Clair;T.L.St.Clair;M.J.Bowden;S.R.Turner(Ed.)
  6. J. Polym. Sci.: Polym. Chem. Ed. v.12 J.H.kawakami;G.T.Kwiatkowski;G.L.Brode;A.W.Bedwin
  7. J, Polym. Sci.: Polym. Chem. Ed. v.23 T.Takekoshi;J.E.Kochanowski;J.S.Manello;M.J.Wedder
  8. J. Polym. Sci.: Polym. Symp. v.74 T.Takekoshi;J.E.Kochanowski;J.S.Manello;M.J.Webber
  9. J. Appl. Polym. Sci. v.32 T.Kaneda;T.Katsura;K.Nakagawa;H.Makino
  10. J. Appl. Polym. Sci. v.32 T.Kaneda;T.Katsura;K.Nakagawa;H.Makno
  11. J. Polym. Sci.: Polym. Sci.; Polym. Chem. Ed. v.12 G.L.Brode;J.H.Kawakami;G.T.Kwiatwowski;A.W.Bedwin
  12. J. Polym. Sci.: Polym. Chem. Ed. v.12 G.T.Kwiatkowski;G.L.Brode;J.H.Kawakami;A.W.Bedwin
  13. Polym. Eng. and Sci. v.24 M.Kochi;I.Mita
  14. J. Appl. Polym. Sci. v.26 H.Sheffer
  15. Ang. MaRromol. Chem. v.107 S.Miti;A.Ray;M.Maiti