폴리비닐알코올섬유에 관한 연구(I)-방사방법이 섬유특성에 미치는 영향-

A Study on the Polyvinylalcohol Fiber(I)-Effect of Spinning Method on the Fiber Properties-

  • 김병철 (한국과학기술원 고분자연구부) ;
  • 김승규 (단국대학교 섬유공학과, 한국과학기술원 고분자연구부, 한국과학기술원 고분자연구부, 한국과학기술원 고분자연구부)
  • 발행 : 1994.07.01

초록

Polyvinylalcohol(PVA) was obtained by low temperature saponification of polyvinylacetate in methanol by NaOH. PVA fibers were prepared by dry-jet wet spinning of either a solution in ethylene glycol(EC) containing boric acid or a solution in the mixture of dimethylsulfoxide(DMSO) and water. Of the two methods tested, the DMSO process produced fibers with smoother surface and more uniform microstructure than the EG process. Further, the former gave rise to higher degree of crystallinity and accommodated greater draw ratio than the latter However, the spinning method had little effect on the resultant crystalline structure.

키워드

참고문헌

  1. U. S. Pat., 5229057 Kuraray Company Ltd.
  2. U. S. Pat., 5154955 Ceram Sna Inc.
  3. G. B. Pat., 2131843 T&N Matls Res Ltd.
  4. U. S. Pat., 5110678 Kuraray Company Ltd.
  5. J. Appl. Polym. Sci. v.43 R.Schellekens;C.Bastiaansen
  6. E. P. Pat., 438780 Kuraray Company Ltd.
  7. U. S. Pat., 5208104 Toray Industries Inc.
  8. U. S. Pat., 5264173 Unitika Ltd.
  9. U. S. Pat., 4440711 Allied Co.
  10. U. S. Pat., 3124562 Kurashiki Rayon Co., Ltd.
  11. U. S. Pat., 4463138 Allied Co.
  12. Polym. J. v.24 no.1 T.Yamamoto;R.Fukae;T.Saso;O.Sangen;M.Kamachi;T.Sato;Y.Fukunishi
  13. U. S. Pat., 5208104 Toray Industries Inc.
  14. U. S. Pat., 3826298 Kuraray Company Ltd.
  15. U. S. Pat., 3660556 Kurashiki Rayon Co.
  16. Polym. J. v.22 T.Yamamoto;S.Seki;R.Fukae
  17. Polyvinyl Alcohol Fibers I.Sakurada
  18. Interscience X-Ray Diffraction Methods in Polymer Science L.E.Alexander
  19. Nippon KagaRu Zasshi v.80 T.Mochizuki
  20. Nippon KagaRu Zasshi v.80 T.Mochizuki