Journal of Photoscience
- 제1권2호
- /
- Pages.89-94
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- 1994
- /
- 1225-8555(pISSN)
A PHOTOCHEMICAL REACTION OF DECABORANE WITH TRIMETHYLSILYLDIAZOMETHANE
-
Sung, Dae-Dong
(Department of Chemistry,Dong-A University)
;
- Kim, Chang-Soo (Department of Chemistry,Dong-A University) ;
- Lee, Jae-Duck (Department of Chemistry,Dong-A University) ;
-
Lim, Gui-Taek
(Department of Chemistry,Dong-A University)
;
- Uhm, Tae-Seop (Department of Chemistry,Dong-A University) ;
- Park, Yong Tae (Department of Chemistry,Dong-A University)
- 발행 : 1994.06.01
초록
The reaction of decaborane with trimethylsilyldiazomethane gives 1, 2-bis (trimethylsilyl)-1, 2-carba-closo-dodecaborane(12). This compound is similar to the icosahedral cage structure of o-carborane. This formation of the first adduct proceeds through deprotonation of the acidic center of B(9) and B(6) by intermolecular attack by the lone electron pair of the carbene, : CHSiMe$_3$. The yield of product is influenced by irradiation and thermal conditions.
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