한국응용과학기술학회지 (Journal of the Korean Applied Science and Technology)

  • 제10권1호
  • /
  • Pages.83-91
  • /
  • 1993
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  • 1225-9098(pISSN)
  • /
  • 2288-1069(eISSN)
한국응용과학기술학회 (The Korean Society of Applied Science and Technology)
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긴사슬 알킬 우로칸에스테르의 합성 및 유기물질에서의 가용성

Synthesis of Long Chain Alkyl Urocanate and Solubilization in Organic Solvent

  • 노윤찬 (충북대학교 공과대학 공업화학과) ;
  • 정환경 (충북대학교 공과대학 공업화학과) ;
  • 남기대 (충북대학교 공과대학 공업화학과) ;
  • 이진희 (태평양 화학(주))
  • Ro, Y.C. (Department of Industrial Chemical Engineering, College of Engineering, Chung Buk National University) ;
  • Jeong, H.K. (Department of Industrial Chemical Engineering, College of Engineering, Chung Buk National University) ;
  • Nam, K.D. (Department of Industrial Chemical Engineering, College of Engineering, Chung Buk National University) ;
  • Lee, J.H. (Pacific Chemical Co., LTD.)
  • 발행 : 1993.05.31
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초록

The syntheses of urocanic acid esters was optimized, starting from p-toluenesulfonic acid salt of this acid and long chain fatty alcohols in the organic solvent and extracting water from it by means of azeotropic Compound. The salts of these urocanic acid esters showed amphoteric properties, but their micellization enhances their rate of hydrolysis leading to the free amine. Nevertheless the long chain gives to the esters themselves an amphoteric character allowing their solubilization in micellar media and in microemulsions the result, yield could enhanced.

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