한국응용과학기술학회지 (Journal of the Korean Applied Science and Technology)
- 제10권1호
- /
- Pages.83-91
- /
- 1993
- /
- 1225-9098(pISSN)
- /
- 2288-1069(eISSN)
DOI QR Code
긴사슬 알킬 우로칸에스테르의 합성 및 유기물질에서의 가용성
Synthesis of Long Chain Alkyl Urocanate and Solubilization in Organic Solvent
- Ro, Y.C. (Department of Industrial Chemical Engineering, College of Engineering, Chung Buk National University) ;
- Jeong, H.K. (Department of Industrial Chemical Engineering, College of Engineering, Chung Buk National University) ;
- Nam, K.D. (Department of Industrial Chemical Engineering, College of Engineering, Chung Buk National University) ;
- Lee, J.H. (Pacific Chemical Co., LTD.)
- 발행 : 1993.05.31
초록
The syntheses of urocanic acid esters was optimized, starting from p-toluenesulfonic acid salt of this acid and long chain fatty alcohols in the organic solvent and extracting water from it by means of azeotropic Compound. The salts of these urocanic acid esters showed amphoteric properties, but their micellization enhances their rate of hydrolysis leading to the free amine. Nevertheless the long chain gives to the esters themselves an amphoteric character allowing their solubilization in micellar media and in microemulsions the result, yield could enhanced.
키워드