대한화학회지 (Journal of the Korean Chemical Society)

  • 제37권7호
  • /
  • Pages.662-671
  • /
  • 1993
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

Ambidentate 리간드의 금속착물 (제 8 보). Isonitrosomethylacetoacetate Imine 리간드의 니켈(II) 및 팔라듐(II) 착물

Metal Complexes of Ambidentate Ligand (VIII). Ni (II) and Pd (II) Complexes of Isonitrosomethylacetoacetate Imines

  • 구본창 (경북대학교 공과대학 공업화학과) ;
  • 최강열 (경북대학교 공과대학 공업화학과) ;
  • 이만호 (경북대학교 공과대학 공업화학과) ;
  • 김인환 (대구대학교 사범대학 화학교육과)
  • Bon-Chang Goo (Department of Industrial Chemistry, Kyungpook National University) ;
  • Gang-Yeol Choi (Department of Industrial Chemistry, Kyungpook National University) ;
  • Man-Ho Lee (Department of Industrial Chemistry, Kyungpook National University) ;
  • In-Whan Kim (Department of Chemistry Education, Taegu University)
  • 발행 : 1993.07.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

isonitrosomethylacetoacetate(H-IMAA)의 이민유도체를 리간드로하는 새로운 Ni(II) 및 Pd(II)착물, Ni(IMAA-NH)(IMAA-NH'), Ni(IMAA-NH)(IMAA-NR),$ Pd(IMAA-NH)_2$, 및 $Pd(IMAA-NR)_2(R=CH_3,\;n-C_3H_7,\;n-C_4H_9$, 또는 $CH_2C_6H_5)$을 합성하고, 이들 착물의 구조를 원소분석, 전자흡수분광법, 적외선흡수분광법, $^1H$ 및 $^{13}C$ 핵자기공명분광법으로 조사하였다. 여기서 H-IMAA-MH 및 H-IMAA-NR은 각각 isonitrosomethylacetoacetate imine 및 N-alkylisonitrosomethylacetoacetate imine 유도체를 나타낸다.

New Ni(II) and Pd(II) complexes of isonitrosomethylacetoacetate imine derivatives, Ni(IMAA-NH)(IMAA-NH'), Ni(IMAA-NH)(IMAA-NR), $Pd(IMAA-NH)_2\;and Pd(IMAA-NR)_2(R=CH_3,\;C_2H_5,\;n-C_3H_7,\;n-C_4H_9,\;or\;CH_2C_6H_5)$, where H-IMAA-NH and H-IMAA-NR represent isonitrosomethylacetoacetate imine and N-alkylisonitrosomethylacetoacetate imine derivative, respectively, have been prepared and the structures of the complexes have been studied by elemental analyses, electronic, infrared, and $^1H-\;and\;^{13}C-NMR$ spectroscopies.

키워드

참고문헌

  1. Cood. Chem. Rev. v.13 A. Chakravorty
  2. Aust. J. Chem. v.23 M. J. Lacey;C. G. Macdonald;J. S. Shannon;P. J. Collin
  3. J. Inorg. Nucl. Chem. v.34 K. S. Bose
  4. Inorg. Nucl. Chem. v.12 R. R. Iyengar;K. S. Bose;C. C. Patel
  5. J. Korean Chem. Soc. v.22 M.-H. Lee;D.-S. Oh;K.-W. Lee
  6. J. Korean Chem. Soc. v.24 M.-H. Lee;D.-S. Oh;S.-H. Kim
  7. J. Korean Chem. Soc. v.35 Y.-S. Jun;M.-H. Lee;I.-W. Kim;S.-H. Kim
  8. Chem. Commun. M. J. Lacey;C. G. Macdonald;J. F. McCoonnel;J. S. Shannon
  9. Inorg. Chem. v.12 K. S. Bose;B. C. Sharma;C. C. Patel
  10. J. Chem. Soc. no.A D. A. White
  11. J. Korean Chem. Soc. v.22 M.-H. Lee;D.-S. Oh;K.-W. Lee
  12. J. Korean Chem. Soc. v.26 T.-S. O;M.-H. Lee;S.-H. Kim;J.-H. Park;H.-W. Lee
  13. J. Chem. Soc. T. W. J. Talor;E. K. Ewbank
  14. J. Chem. Soc. C. Djordjevic;J. Lewis;R. S. Nyholm
  15. Tetrahedron Lett. K. G. Das;D. N. Sen;N. Thankarajan
  16. J. Inorg. Chem. v.13 A. V. Ablov;V. N. Zubarov;Russ
  17. J. Chem. Educ. v.38 W. Manch;W. C. Fernelius
  18. J. Phys. Chem. v.65 R. A. Krause;N. B. Colthyp;D. H. Busch
  19. Org. Reac. v.7 R. Adams
  20. Bull. Soc. Chem. Fr. J. Fabian;M. Legrand;P. Porier
  21. G.-Y. Choi;M.-H. Lee;I.-W. Kim
  22. J. Org. Chem. v.23 D. H. Macdaniel;H. C. Brown
  23. Physical Organic Chemistry (2nd Ed.) J. Hine
  24. Advanced Organic Chemistry (2nd Ed.) F. A. Carey;R. J. Sundberg