$ZrO_2$와 NiTi 합금의 반응접합 : 분석투과전자현미경을 이용한 $ZrO_2/NiTi$ 접합층 반응생성물 분석

Reaction Bonding of $ZrO_2$ and NiTi : Reaction Products Analyses on $ZrO_2/NiTi$ Bonding Interface with AEM

  • 김영정 (성화대학교 이공학부 재료공학과) ;
  • 김환 (서울대학교 공과대학 무기재료공학과)
  • Kim, Young-Jung (Department of Materials Science and Engineering, Sunghwa Uinversity) ;
  • Kim, Hwan (Department of Inorganic Materials Engineering, Seoul national University)
  • 발행 : 1993.11.01

초록

Microstructural development at the ZrO2/NiTi bonding interface and reaction products were examined and identified with SEM and AEM. Ti-oxide, Ti2Ni and Ni2Ti layer were observed whose thickness depends on bonding temperature typically. The development of Ti-oxide layer is related with oxygen ion in ZrO2 and liquid phase Ti2Ni. It is considered that compositional deviation from homogeneity and residual stress caused by thermal expansion mismatch are closely related with the formation of the Ti2Ni phase.

키워드

참고문헌

  1. 한국요업학회 v.28 no.8 $ZrO_2$와 NiTi 합금의 고상접합; (Ⅰ) 접합의 최적 조건 및 접합강도 김영정;김환
  2. Ceramic Microstructures '86 Role of Interfaces, Materials Science Research v.21 The Roll of Interfacial Reactions on the Mechanical Properties of Ceramic Brazements A.J. Moorhead;H.M. Henson;TJ. Henson;J.A. Pask(ed.);A.G. Evans(ed.)
  3. Intermetallic Compounds ch. 13 Miscellaneous Structures of Fixed Stoichiometry M.V. Nevitt;J.H. Westbrook(ed.)
  4. Metallurgical Transactions v.2 Homogeneity Range and the Martenstic Transformation in NiT₁ R.J. Wasilewski;S.R. Butler;J.E. Hanlon;D. Worden
  5. Journal of Applid Physics v.34 no.5 Effect of Low-Temperature Phase Changes on the Mechanical Properties of Alloys Near Composition TiNi W.J. Buehler;J.V Gulfrich;R.C. Wiley