한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제30권2호
  • /
  • Pages.123-130
  • /
  • 1993
  • /
  • 1229-7801(pISSN)
  • /
  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
권호 표지

알콕사이드로부터 $Al_2O_3-SiC$ 복합재료의 제조 및 특성

Synthesis and Properties of $Al_2O_3-SiC$ Composites from Alkoxides

  • 이홍림 (연세대학교 공과대학 세라믹공학과) ;
  • 김규영 (연세대학교 공과대학 세라믹공학과)
  • 발행 : 1993.02.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Dispersed type Al2O3-SiC composite powders were synthesized from Al-isopropoxide (Al(i-OC3H7)3) and Si(OC2H5)4 precursors by hydrolysis of mixed alkoxides and carbothermal reaction method. The characteristics of the synthesized (dispersed type) Al2O3-SiC composite powders were investigated using XRD, SEM, TEM, BET and particle size analyzer. Carbothermal reaction to produce Al2O3-SiC composite was completed in 10h at 135$0^{\circ}C$ on 3~4㎤/s (0.21~0.28cm/s) of H2 flow rate and about 1/1 of carbon/oxides(=SiO2＋Al2O3) molar ratio. The synthesized powders were observed to have the mean particle size range of 0.4~1.26${\mu}{\textrm}{m}$ and showed finer particle size with increasing SiC content.

키워드

참고문헌

  1. Acta Metal. v.34 no.7 Transient Stress in Bimodal Compacts During Sintering L.C. Dejonghe;N.N. Rahaman;C.H. Hsueh
  2. J. Am. Ceram. Soc. v.70 no.10 Sintering with Rigid Inclusions G.W. Scherer
  3. Ultrastructure Processing of Ceramics, Glasses and Composites Potential Impact of Ultrastructural Processing on Government and Industry D.R. Ulrich;L.L Hench(ed.)
  4. Yogyo-Kyokai-Shi v.95 no.1 Preparation of Ultrafine SiC Powders by Pyrolysis of Tetramethyldisilane M. Endo;T. Sano;K. Mori;N. Urasato;M. Shirashi
  5. Yogyo-Kyokai-Shi v.95 no.1 Preparation of Composite Particles of SiC-Si₃N₄System by Vapor Reaction Method M. Hojo;H. Maeda;A. Kato
  6. J. Mat. Sci v.20 no.7 Ultrafine Particles of the ZrO₂-SiO₂System Prepared by the Spray-ICP Technique T. Ono;M. Kagawa;Y. Syono
  7. J. Am. Ceram. Soc. v.66 no.11 Stability of Ultrafine Tetragonal ZrO₂ Coprecipitated with Al₂O₃by the Spray-ICP Technique M. Kagawa;M. Kikuchi;Y. Syono
  8. Yogyo-Kyo-kai-Shi v.94 no.4 Preparation of Codeposited Al₂O₃-TiO₂Powders by Vapor Phase Reaction Using Combustion Flame S. Hori;Y. Ishii;M. Yoshimura;S. Somiya
  9. Am. Ceram. Soc. Bull. v.48 no.8 Coprecipitates Yielding MgAl₂O₄Spinel Powders R.J. Bratton
  10. Yogyo-Kyokai-Shi v.93 no.1 Property of SiO₂-Al₂O₃ Powders Prepared from Metal Alkoxide Y. Hirata;H. Minamizono;K. Shimada
  11. Yogyo-Kyokai-Shi v.96 no.6 Preparation of Mullite Powders from Metal Alkoxide by Ultrasonic Spray Pyrolysis O. Sakurai;N. Mizutani;M. Kato
  12. J. Am. Ceram. Soc. v.72 no.11 In Situ Polysilane-Derived Silicon Carbide Particulates Dispersed in Silicon Nitride Composite R. Riedal;K. Strecker;G. Petzow
  13. J. Non-Crystal. Sol. v.48 History and Principles of the Sol-Gel Process and Some New Multicomponent Oxide Coating H. Dislich;P. Hinz
  14. Elements of X-ray Diffraction Published B.D. Cullity
  15. J. Am. Ceram. Soc. v.70 no.k3 Crystallization Behavior of Al₂O₃in the Presence of SiO₂ A.K. Chakravotry;D.K. Ghosh
  16. Am. Ceram. Soc. Bull. v.54 no.2 Formation of Silicon Carbide from Rice Hulls J.G. Lee;I.B. Cutler
  17. J. Am. Ceram. Soc. v.49 no.7 Reaction Between Silica and Graphite N. Klinger;E.L. Strauss;K.L. Komarek
  18. J. Kor. Ceram. Soc. v.23 no.1 Synthesisk of SiC and SiC-Si₃N₄ Powder from Jecheon Quartz H.L. Lee;C.H. Bai
  19. J. Am. Ceram. Soc. v.75 no.8 Al₂O₃-SiC Composites from aluminosilicate Precursor A.C.D. Chaklader (et al.)
  20. J. Am. Ceram. Soc. v.63 no.5-6 Reaction of Clay and Carbon to form and Separate Al₂O₃and SiC B. Bechtold;I.B. Cutler
  21. J. Am. Ceram. Soc. v.66 no.7 Beta SiC Powders Produced by Carbothermic Reduction of Silica in a High-Temperature Rotary Furnace G.C. Wei
  22. J. Mat. Sci. Lett. v.8 Carbothermal Reduction Process of Precursors Derived from Alkoxides for Synthesis of Boron-Doped SiC Powder Y. Sugahara;Y. Takeda;K. Kuroda;C.Kato
  23. J. Am. Ceram. Soc. v.62 no.3-4 The Reduction of Silica with Carbon and Silicon Carbide P.D. Miller;J.G. Lee;I.B. Cutler
  24. Ph.D. Thesis Studies on the Behavior of Stacking Faults in SiC Ceramics W.S. Seo