Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Poling and Properties in the Polymer/organic Low Weight Molecule System

고분자/유기저분자계에서의 분극과 물성

  • 조재환 (건국대학교 공과대학 섬유공학과) ;
  • 김창경 (전남대학교 공과대학 섬유공학과)
  • Published : 1993.05.01

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Abstract

Thermal, structural and morphological characteristics were investigated in the unpoled and poled polymer/organic low weight molecule systems, that is. p-nitroaniline(p-NA) and 2-methyl-4-nitroaniline (HHA)/poly(ethylene oxide) (PEO) films. Good P-HA/PEO and HHA/PEO films could be obtained from the mixtures having 50% p-NA or less. and the films containing 30% P-NA or less could be drawn. Differential scanning calorimetric measurements showed not only two strong melting peaks due to the melting of P-NA and PEO crystals but also a weak melting peak due to the interaction of two components. p-NA and MNA crystals were observed to have a short bar structure, whereas p-NA/PEO films were observed to have an entangled structure. Poling of P-HA/PEO films caused a good reorientation of p-HA crystals observed with the scanning electron microscope but such a phenomenon was not shown in the MNA/PEO films. A significant change of X-ray diffraction peaks appeared for the poled P-HA/PEO films.

Keywords