Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
권호 표지

Determination of Trace Elements in Atmospheric Dust by X-Ray Fluorescence Spectrometry(II) : X-ray Fluorescence Spectrometric Determination of Light Elements

형광 X선에 의한 대기분진중의 미량성분의 측정(II): 대기부유분진 중 경원소의 X-선 형광분석

  • Published : 1993.09.01
Download PDF
⟨ Previous Next ⟩

Abstract

A simple and direct method is developed for the determination of light Elements in atmospheric particulates by X-ray fluorescence spectrometry. Calibration standards for the light elements such as Al, Mg, K, Ca, etc are prepared by filtering real atmospheric particulates over variable time and subsequently standardizing them by Inductively Coupled Plasma-Mass Spectrometry(ICP-MS) or Atomic Absorption Spectrophotometry(AAS) analysis. The validity of this calibration method is tested by analyzing more than 100 aerosol samples, collected at urban(Seoul) and rural(Padori) sites over a two year period with this method and then comparing them with those by other accuracy proven methods such as AAS or ICP-MS: for all metals tested the results showed reasonably good agreements (R $\geq$ 0.95).

Keywords

References

  1. 한국대기보전학회지 v.5 no.2 형광 X-선에 의한 대기 부유분진중 미량성분의 측정(Ⅰ) 이용근;맹현재;이보경;황규자
  2. 연세대학교 대학원 석사학위논문 점적거름종이를 이용한 망간단괴의 X-선 형광분석 황의성
  3. Tellus v.41B Seasonal Variability of the Elemental Composition of Atmospheric Aerosol Particles over the Northwestern Mediterranean Bergametti,G.;A.L.Dutot;P.Buat-Menard;R.Losno;E.Remoudaki
  4. Anal. Chem. v.45 no.12 X-ray Spectrometry for Particulate Air Pollution-A Quantitative Comparison of Techniques Gilfrich,J.V.;P.G.Burkhalter;L.S.Birks
  5. J. Japan Soc. Air Pollut. v.10 no.3 Determination of Metals in Airborn Dust by Fluorescent X-ray Spectrometry Himi,Y.;F.Muramatsu
  6. Talanta v.17 Determination of Atmospheric Iron Particulate by X-ray Fluorescence Spectroscopy Hwang,J.Y.
  7. Anal. Chem. v.58 no.6 Developement of National Bureau of Standards Thin Glass Films for X-ray Fluorescence Spectrometry Pella,P.A.;D.E.Newbury;E.B.Steel
  8. Anal. Chim. Acta. v.110 The Determination of Metals at ppb Levels by Thin Film X-ray Fluorescence Spectrometry after Coprecipitation with a Molybdenum Carrier Complex Pik,A.J.;A.J.Cameron;K.L.Williams
  9. Japan Analyst v.18 Determination of Metals in Airborne Dust by Fluorescent X-ray Spectrometry with Filter Paper Technique Shono,T.;K.Shinra
  10. Japan Analyst v.10 Determination of Thorium in Uranium Metal by Fluorescent X-ray Spectrometry with Filter Paper Technique Takeuchi,T.;T.Fukasawa;T.Sekiya
  11. J. Japan Soc. Air Pollut. v.22 no.4 Investigation of the Standardization of Measurement for Metal Element in Aerosols by X-ray Fluorescence Analysis Tanaka,S.;Y.Hashimoto
  12. Japan Analyst v.39 no.7 A Correction Method for the Determination of Low Atomic Number Elements in Aerosols by XRF Analysis by Using an Intensity Ratio between Compton and Thomson Scattering Tanaka,S.;Y.Hashimoto;S.Sato