Characterization of Inorganic Chemicals in Total Suspended Particulates and a Source Apportionment by Chemical Mass Balance Model

대기 분진의 무기 화학적 조성 분석과 Chemical Mass Balance에 의한 오염원 기여도 산출

  • Seo, Young-Hwa (Dept. of Civil Engineering Korea Advanced Institute of Science and Technology) ;
  • Koo, Ja-Kong (Dept. of Civil Engineering Korea Advanced Institute of Science and Technology)
  • 서영화 (한국과학기술원 토목공학과 환경시스템연구실) ;
  • 구자공 (한국과학기술원 토목공학과 환경시스템연구실)
  • Received : 1992.04.17
  • Published : 1992.06.01

Abstract

Twenty four metal, nonmetal elements and 4 major anions in total suspended particulates (TSP) collected at two sites in Daejon city from october to december in 1991 by a Hi-vol sampler were thoroughly analyzed by Inductively Coupled Plasma/ Atomic Emission Spectrometry (ICP/AES) and Ion Chromatography (IC). These analyzed data were used to perform a receptor modeling using the Chemical Mass Balance (CMB) for the source apportionment of TSP sample. Approximately 60% TSP weight in industrial complex area was influenced by potential industrial sources and 25% was by heating fuels and automobile emissions, whereas a half of TSP in residential area was influenced by surrounding environment and more than 35% of TSP was influenced by heating fuels. The CMB model provided source apportionment results reasonably and scientifically with a minor limitation.

Keywords

References

  1. 대기보전학회지 v.6 no.1 황사의 양적 추정을 위한 기초연구 김동술
  2. 대기보전학회지 v.6 no.2 Target Transformation Factor Analysis를 이용한 부산시 분진오염원의 양적 추정 김태오;김동술;나진균
  3. 대전 제 1, 2 공업 단지 각 업체의 대기 오염 배출시설 현황 자료 대전 지방 환경청
  4. 대전 제 1, 2 공업 단지내 거주업체의 현황 자료 대전 제 1, 2 공업 단지 관리 사무소
  5. 대기보전학회지 v.6 no.2 황사현상시의 대기오염물질 동태에 관한 연구 이민희;황규호;김은식;平井英二;丁子哲治;宮崎元
  6. 대기보전학회지 v.4 no.2 이단 필터 샘플러에 의한 대기 부유 분진의 포집 및 금속 성분의 계절별 거동에 관한 연구 이용근;김남훈;명노승;황규자
  7. 대기보전학회지 v.5 no.2 형광 X선에 의한 대기 부유 분진중의 미량 성분의 측정 (I) 이용근;맹현재;이보경;황규자
  8. Anal. Chem. v.54 Inductively Coupled Plasma Optical Emission Spectrometry for the Analysis of Aerosol Samples Collected by Cascade Impactors Broekaert,J.A.C.;Wopenka,B.;Puxbaum,H.
  9. 84th Annual Meeting & Exhibition, Vancouber, British, Columbia, paper #91-52.1 Source apportionment of PM2.5 in Phoenix, Arizona Chow,J.C.;Watson,J.G.;Lowenthal,D.H.;Frazier,E.C.A.;Prichett,L.C.
  10. Standard Method for the Examination of Water and Wastewater(17th Edition) Clesceri,L.S.;Greenberg,A.E.;Trussell,R.R.(ed.)
  11. Environ. Sci. Technol. v.25 Multimodal Size Spectra of Submicrometer Particles Bearing Various Elements in Rural Air Dodd,J.A.;Ondov,J.M.;Tuncel,G.;Dzubay,T.G.;Stevens,R.K.
  12. Anal. Chem. v.63 Automated Scanning Electron Microscopy for Atmospheric Particle Analysis Germani,M.S.;Buseck,P.R.
  13. J. Air Waste Manage. Assoc. v.41 Source Apportionment with Site Specific Source Profiles Glover,D.M.;Hopke,P.K.;Vermette,S.J.;Landsberger,S.;D'Auben,D.R.
  14. Receptor modeling in Environmental Chemistry Hopke,P.K.
  15. Chemical Mass Balance Receptor Model User's Manual, EPA-450/4-83-014 v.Ⅲ Receptor Model Technical Series U. S. Environmental Protection Agency
  16. EPA 450/4-85-002 Receptor Model Source Composition Library U. S. Environmental Protection Agency
  17. NC 27717 VOC/PM Speciation Data System USEPA/Office of Air of Air Quality Planning and Standard, RTP U. S. Environmental Protection Agency
  18. J. Air Pollu. Control Assoc. v.34 Overview of Receptor Model Principles Watson,J.G.